π-Expanded borazine: An ambipolar conjugated B-π-N macrocycle

Pangkuan Chen; Roger A. Lalancette; Frieder Jäkle

doi:10.1002/anie.201203788

π-Expanded borazine: An ambipolar conjugated B-π-N macrocycle

Pangkuan Chen, Roger A. Lalancette, Frieder Jäkle

Rutgers Newark, Chemistry

Research output: Contribution to journal › Article › peer-review

123 Scopus citations

Abstract

Staying at a B 'N' B: A highly symmetric cyclic structure in which N donor and B acceptor sites are alternating (see picture) is found for the first ambipolar π-conjugated B-N macrocycle. The donor-π-acceptor arrangement results in mutual interactions between B and N and a pronounced solvatochromic effect on the emission. The strong luminescence in solution also lends itself to use in anion recognition.

Original language	English (US)
Pages (from-to)	7994-7998
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	32
DOIs	https://doi.org/10.1002/anie.201203788
State	Published - Aug 6 2012

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Keywords

ambipolar
anion recognition
luminescence
macrocycle
organoborane

Access to Document

10.1002/anie.201203788

Cite this

@article{6038784a3ebf4826b69b0d099d0d74bf,

title = "π-Expanded borazine: An ambipolar conjugated B-π-N macrocycle",

abstract = "Staying at a B 'N' B: A highly symmetric cyclic structure in which N donor and B acceptor sites are alternating (see picture) is found for the first ambipolar π-conjugated B-N macrocycle. The donor-π-acceptor arrangement results in mutual interactions between B and N and a pronounced solvatochromic effect on the emission. The strong luminescence in solution also lends itself to use in anion recognition.",

keywords = "ambipolar, anion recognition, luminescence, macrocycle, organoborane",

author = "Pangkuan Chen and Lalancette, {Roger A.} and Frieder J{\"a}kle",

year = "2012",

month = aug,

day = "6",

doi = "10.1002/anie.201203788",

language = "English (US)",

volume = "51",

pages = "7994--7998",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "32",

}

TY - JOUR

T1 - π-Expanded borazine

T2 - An ambipolar conjugated B-π-N macrocycle

AU - Chen, Pangkuan

AU - Lalancette, Roger A.

AU - Jäkle, Frieder

PY - 2012/8/6

Y1 - 2012/8/6

N2 - Staying at a B 'N' B: A highly symmetric cyclic structure in which N donor and B acceptor sites are alternating (see picture) is found for the first ambipolar π-conjugated B-N macrocycle. The donor-π-acceptor arrangement results in mutual interactions between B and N and a pronounced solvatochromic effect on the emission. The strong luminescence in solution also lends itself to use in anion recognition.

AB - Staying at a B 'N' B: A highly symmetric cyclic structure in which N donor and B acceptor sites are alternating (see picture) is found for the first ambipolar π-conjugated B-N macrocycle. The donor-π-acceptor arrangement results in mutual interactions between B and N and a pronounced solvatochromic effect on the emission. The strong luminescence in solution also lends itself to use in anion recognition.

KW - ambipolar

KW - anion recognition

KW - luminescence

KW - macrocycle

KW - organoborane

UR - http://www.scopus.com/inward/record.url?scp=84864778309&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84864778309&partnerID=8YFLogxK

U2 - 10.1002/anie.201203788

DO - 10.1002/anie.201203788

M3 - Article

C2 - 22767496

AN - SCOPUS:84864778309

SN - 1433-7851

VL - 51

SP - 7994

EP - 7998

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 32

ER -

π-Expanded borazine: An ambipolar conjugated B-π-N macrocycle

Abstract

All Science Journal Classification (ASJC) codes

Keywords

Access to Document

Other files and links

Fingerprint

Cite this