A metal mediated [6 + 3] cycloaddition reaction. Coupling of azirines and cycloheptatriene.

Karen Chaffee, Hanan Morcos, John B. Sheridan

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

UV irradiation of tricarbonyl(cycloheptatriene)chromium(0) and 2-phenyl-1-azirines through pyrex at 0° C leads to 7-aza-8-phenylbicyclo[4.3.1]deca-2,4,7-trienes via a [6 + 3] cycloaddition of the azirine to the cycloheptatriene ring.

Original languageEnglish (US)
Pages (from-to)1577-1580
Number of pages4
JournalTetrahedron Letters
Volume36
Issue number10
DOIs
StatePublished - Mar 6 1995
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Fingerprint

Dive into the research topics of 'A metal mediated [6 + 3] cycloaddition reaction. Coupling of azirines and cycloheptatriene.'. Together they form a unique fingerprint.

Cite this