A UV spectroscopic study of DMZn and DMCd chemisorbed on quartz surfaces

Ping S. Shaw; Esaul Sanchez; Zhen Wu; Richard M. Osggod

doi:10.1016/0009-2614(88)85167-4

A UV spectroscopic study of DMZn and DMCd chemisorbed on quartz surfaces

Ping S. Shaw, Esaul Sanchez, Zhen Wu, Richard M. Osggod

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Abstract

The ultraviolet (UV) transmission spectra of dimethylzinc (DMZn) and dimethylcadmium (DMCd) chemisorbed on quartz surfaces have been measured between 190 and 290 nm. Using chemisorption spectra obtained after different thermal pretreatments of the SiO₂ substrate, it is shown that the surface hydroxyl groups play a crucial role in the chemisorption of DMZn and DMCd molecules at 300 K. Spectral changes due to thermal effects and low-power, 248 and 193 nm excimer-laser irradiation are compared and the differences are discussed.

Original language	English (US)
Pages (from-to)	449-454
Number of pages	6
Journal	Chemical Physics Letters
Volume	151
Issue number	4-5
DOIs	https://doi.org/10.1016/0009-2614(88)85167-4
State	Published - Oct 21 1988
Externally published	Yes

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(88)85167-4

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@article{028a884c9cfb40a2b376164d2ff0664c,

title = "A UV spectroscopic study of DMZn and DMCd chemisorbed on quartz surfaces",

abstract = "The ultraviolet (UV) transmission spectra of dimethylzinc (DMZn) and dimethylcadmium (DMCd) chemisorbed on quartz surfaces have been measured between 190 and 290 nm. Using chemisorption spectra obtained after different thermal pretreatments of the SiO2 substrate, it is shown that the surface hydroxyl groups play a crucial role in the chemisorption of DMZn and DMCd molecules at 300 K. Spectral changes due to thermal effects and low-power, 248 and 193 nm excimer-laser irradiation are compared and the differences are discussed.",

author = "Shaw, {Ping S.} and Esaul Sanchez and Zhen Wu and Osggod, {Richard M.}",

note = "Funding Information: The authors would like to thank Zhong Lu and Chien F. Yu for their help with UHV surface experiments and also James A. O{\textquoteright}Neill and Rob Scarmozzinof or many very helpful discussions.T his work is supported by the Department of Army (ARO) and IBM.",

year = "1988",

month = oct,

day = "21",

doi = "10.1016/0009-2614(88)85167-4",

language = "English (US)",

volume = "151",

pages = "449--454",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

number = "4-5",

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TY - JOUR

T1 - A UV spectroscopic study of DMZn and DMCd chemisorbed on quartz surfaces

AU - Shaw, Ping S.

AU - Sanchez, Esaul

AU - Wu, Zhen

AU - Osggod, Richard M.

N1 - Funding Information: The authors would like to thank Zhong Lu and Chien F. Yu for their help with UHV surface experiments and also James A. O’Neill and Rob Scarmozzinof or many very helpful discussions.T his work is supported by the Department of Army (ARO) and IBM.

PY - 1988/10/21

Y1 - 1988/10/21

N2 - The ultraviolet (UV) transmission spectra of dimethylzinc (DMZn) and dimethylcadmium (DMCd) chemisorbed on quartz surfaces have been measured between 190 and 290 nm. Using chemisorption spectra obtained after different thermal pretreatments of the SiO2 substrate, it is shown that the surface hydroxyl groups play a crucial role in the chemisorption of DMZn and DMCd molecules at 300 K. Spectral changes due to thermal effects and low-power, 248 and 193 nm excimer-laser irradiation are compared and the differences are discussed.

AB - The ultraviolet (UV) transmission spectra of dimethylzinc (DMZn) and dimethylcadmium (DMCd) chemisorbed on quartz surfaces have been measured between 190 and 290 nm. Using chemisorption spectra obtained after different thermal pretreatments of the SiO2 substrate, it is shown that the surface hydroxyl groups play a crucial role in the chemisorption of DMZn and DMCd molecules at 300 K. Spectral changes due to thermal effects and low-power, 248 and 193 nm excimer-laser irradiation are compared and the differences are discussed.

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U2 - 10.1016/0009-2614(88)85167-4

DO - 10.1016/0009-2614(88)85167-4

M3 - Article

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SN - 0009-2614

VL - 151

SP - 449

EP - 454

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4-5

ER -

A UV spectroscopic study of DMZn and DMCd chemisorbed on quartz surfaces

Abstract

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