Accessing Ni(0) to Ni(IV) via nickel-carbon-phosphorus bond reorganization

Lirong Lin; David S. Tresp; Denis M. Spasyuk; Roger A. Lalancette; Demyan E. Prokopchuk

doi:10.1039/d3cc04687g

Accessing Ni(0) to Ni(IV) via nickel-carbon-phosphorus bond reorganization

Lirong Lin, David S. Tresp, Denis M. Spasyuk, Roger A. Lalancette, Demyan E. Prokopchuk

Research output: Contribution to journal › Article › peer-review

Abstract

Two-electron oxidation of a Ni^IIPh(PCP) pincer complex initiates phosphine ligand insertion, generating an η⁶-arylphosphonium moiety coordinated to Ni^II. The reaction is fully reversible under reducing conditions.

Original language	English (US)
Pages (from-to)	674-677
Number of pages	4
Journal	Chemical Communications
Volume	60
Issue number	6
DOIs	https://doi.org/10.1039/d3cc04687g
State	Published - Nov 23 2023
Externally published	Yes

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d3cc04687g

Cite this

@article{89337de7fd5447b0865287b19124b899,

title = "Accessing Ni(0) to Ni(IV) via nickel-carbon-phosphorus bond reorganization",

abstract = "Two-electron oxidation of a NiIIPh(PCP) pincer complex initiates phosphine ligand insertion, generating an η6-arylphosphonium moiety coordinated to NiII. The reaction is fully reversible under reducing conditions.",

author = "Lirong Lin and Tresp, {David S.} and Spasyuk, {Denis M.} and Lalancette, {Roger A.} and Prokopchuk, {Demyan E.}",

note = "Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry.",

year = "2023",

month = nov,

day = "23",

doi = "10.1039/d3cc04687g",

language = "English (US)",

volume = "60",

pages = "674--677",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "6",

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T1 - Accessing Ni(0) to Ni(IV) via nickel-carbon-phosphorus bond reorganization

AU - Lin, Lirong

AU - Tresp, David S.

AU - Spasyuk, Denis M.

AU - Lalancette, Roger A.

AU - Prokopchuk, Demyan E.

PY - 2023/11/23

Y1 - 2023/11/23

N2 - Two-electron oxidation of a NiIIPh(PCP) pincer complex initiates phosphine ligand insertion, generating an η6-arylphosphonium moiety coordinated to NiII. The reaction is fully reversible under reducing conditions.

AB - Two-electron oxidation of a NiIIPh(PCP) pincer complex initiates phosphine ligand insertion, generating an η6-arylphosphonium moiety coordinated to NiII. The reaction is fully reversible under reducing conditions.

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U2 - 10.1039/d3cc04687g

DO - 10.1039/d3cc04687g

M3 - Article

C2 - 38050452

AN - SCOPUS:85179165772

SN - 1359-7345

VL - 60

SP - 674

EP - 677

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Accessing Ni(0) to Ni(IV) via nickel-carbon-phosphorus bond reorganization

Abstract

All Science Journal Classification (ASJC) codes

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