Accessing three oxidation states of cobalt in M6L3nanoprisms with cobalt-porphyrin walls

P. Thomas Blackburn, Iram F. Mansoor, Kaitlyn G. Dutton, Alexei M. Tyryshkin, Mark C. Lipke

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt2+-linked M6L3nanoprisms with cobalt-porphyrin walls were prepared and their redox properties were evaluated electrochemically and chemically, leading to the first time that cobalt-porphyrin nanocages have been characterized in CoI, CoII, and CoIIIstates.

Original languageEnglish (US)
Pages (from-to)11342-11345
Number of pages4
JournalChemical Communications
Volume57
Issue number86
DOIs
StatePublished - Nov 7 2021

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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