Accessing three oxidation states of cobalt in M6L3nanoprisms with cobalt-porphyrin walls

P. Thomas Blackburn; Iram F. Mansoor; Kaitlyn G. Dutton; Alexei M. Tyryshkin; Mark C. Lipke

doi:10.1039/d1cc04860k

Accessing three oxidation states of cobalt in M₆L₃nanoprisms with cobalt-porphyrin walls

P. Thomas Blackburn, Iram F. Mansoor, Kaitlyn G. Dutton, Alexei M. Tyryshkin, Mark C. Lipke

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt²⁺-linked M₆L₃nanoprisms with cobalt-porphyrin walls were prepared and their redox properties were evaluated electrochemically and chemically, leading to the first time that cobalt-porphyrin nanocages have been characterized in Co^I, Co^II, and Co^IIIstates.

Original language	English (US)
Pages (from-to)	11342-11345
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	86
DOIs	https://doi.org/10.1039/d1cc04860k
State	Published - Nov 7 2021

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Accessing three oxidation states of cobalt in M6L3nanoprisms with cobalt-porphyrin walls",

abstract = "Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt2+-linked M6L3nanoprisms with cobalt-porphyrin walls were prepared and their redox properties were evaluated electrochemically and chemically, leading to the first time that cobalt-porphyrin nanocages have been characterized in CoI, CoII, and CoIIIstates.",

author = "Blackburn, {P. Thomas} and Mansoor, {Iram F.} and Dutton, {Kaitlyn G.} and Tyryshkin, {Alexei M.} and Lipke, {Mark C.}",

note = "Funding Information: This work was supported by the ACS Petroleum Research Fund (PRF grant #61015-DNI3). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

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doi = "10.1039/d1cc04860k",

language = "English (US)",

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T1 - Accessing three oxidation states of cobalt in M6L3nanoprisms with cobalt-porphyrin walls

AU - Blackburn, P. Thomas

AU - Mansoor, Iram F.

AU - Dutton, Kaitlyn G.

AU - Tyryshkin, Alexei M.

AU - Lipke, Mark C.

N1 - Funding Information: This work was supported by the ACS Petroleum Research Fund (PRF grant #61015-DNI3). Publisher Copyright: © The Royal Society of Chemistry 2021.

PY - 2021/11/7

Y1 - 2021/11/7

N2 - Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt2+-linked M6L3nanoprisms with cobalt-porphyrin walls were prepared and their redox properties were evaluated electrochemically and chemically, leading to the first time that cobalt-porphyrin nanocages have been characterized in CoI, CoII, and CoIIIstates.

AB - Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt2+-linked M6L3nanoprisms with cobalt-porphyrin walls were prepared and their redox properties were evaluated electrochemically and chemically, leading to the first time that cobalt-porphyrin nanocages have been characterized in CoI, CoII, and CoIIIstates.

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DO - 10.1039/d1cc04860k

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EP - 11345

JO - Chemical Communications

JF - Chemical Communications

IS - 86

ER -

Accessing three oxidation states of cobalt in M₆L₃nanoprisms with cobalt-porphyrin walls

Abstract

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