Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO)

Simon B. Duckett; Richard Eisenberg; Alan S. Goldman

doi:10.1039/C39930001185

Activation of H₂ by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe ₃)₂(μ-H)(μ-Cl)RH(PMe₃)(CO)

Simon B. Duckett, Richard Eisenberg, Alan S. Goldman

SAS - Chem & Chemical Biology

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The oxidative addition of H₂ to [RhCl(CO)(PMe₃) ₂] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

Original language	English (US)
Pages (from-to)	1185-1187
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39930001185
State	Published - Dec 1 1993

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C39930001185

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title = "Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO)",

abstract = "The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.",

author = "Duckett, {Simon B.} and Richard Eisenberg and Goldman, {Alan S.}",

year = "1993",

month = dec,

day = "1",

doi = "10.1039/C39930001185",

language = "English (US)",

pages = "1185--1187",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "15",

}

Activation of H₂ by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe ₃)₂(μ-H)(μ-Cl)RH(PMe₃)(CO). / Duckett, Simon B.; Eisenberg, Richard; Goldman, Alan S.

In: Journal of the Chemical Society, Chemical Communications, No. 15, 01.12.1993, p. 1185-1187.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO)

AU - Duckett, Simon B.

AU - Eisenberg, Richard

AU - Goldman, Alan S.

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