TY - JOUR
T1 - Adsorption of 4-chlorophenol and aniline by nanosized activated carbons
AU - Chen, Chengyu
AU - Geng, Xinhua
AU - Huang, Weilin
N1 - Funding Information:
This study was supported financially by the New Jersey Water Resources Research Institute ( 2014NJ352B ) and China Scholarship Council (CSC) ( 201206150065 ). We gratefully thank Dr. Richard E. Riman at Department of Materials Science and Engineering and Dr. Vikas Nanda at Department of Biochemistry and Molecular Biology of Rutgers University for providing the BET and DLS instruments, respectively. We also acknowledge Dr. Jinhua Wu of South China University of Technology for the assistance in SEM measurements.
Publisher Copyright:
© 2017 Elsevier B.V.
PY - 2017
Y1 - 2017
N2 - Reactive solids injected into aquifers for in situ groundwater remediation should possess both high mobility and great reactivity or adsorption for targeted contaminants. We have shown in a prior study that nanosized activated carbons (NACs) had strong colloidal stability in aquatic environments. The present study investigated the adsorption behavior for the four NACs and two typical aromatic contaminants, 4-chlorophenol (4-CP) and aniline. The adsorption capacities measured for the NACs were compared with those reported for other nanosized adsorbents which were considered as potential candidates for groundwater remediation. Our results indicated that NACs had large specific surface areas (SSAs) and microporosities, and exhibited rapid rates of adsorption that could be quantified with both the pseudo-second-order rate equation and the intra-particle diffusion model. The adsorption equilibria were adequately described with the Freundlich isotherm equation, and hydrophobic interactions were likely the dominating mechanism for the adsorption. The adsorption processes were influenced by solution pH and temperature, whereas background electrolytes showed negligible effect. The tested NACs exhibited adsorption capacities 10–100 times greater for the respective adsorbates when compared to other carbonaceous nano-adsorbents such as carbon nanotubes (CNTs) and graphene derivatives. Such strong adsorbability, along with their high colloidal stability, makes NACs potentially suitable for remedy of aquifers contaminated with organic pollutants.
AB - Reactive solids injected into aquifers for in situ groundwater remediation should possess both high mobility and great reactivity or adsorption for targeted contaminants. We have shown in a prior study that nanosized activated carbons (NACs) had strong colloidal stability in aquatic environments. The present study investigated the adsorption behavior for the four NACs and two typical aromatic contaminants, 4-chlorophenol (4-CP) and aniline. The adsorption capacities measured for the NACs were compared with those reported for other nanosized adsorbents which were considered as potential candidates for groundwater remediation. Our results indicated that NACs had large specific surface areas (SSAs) and microporosities, and exhibited rapid rates of adsorption that could be quantified with both the pseudo-second-order rate equation and the intra-particle diffusion model. The adsorption equilibria were adequately described with the Freundlich isotherm equation, and hydrophobic interactions were likely the dominating mechanism for the adsorption. The adsorption processes were influenced by solution pH and temperature, whereas background electrolytes showed negligible effect. The tested NACs exhibited adsorption capacities 10–100 times greater for the respective adsorbates when compared to other carbonaceous nano-adsorbents such as carbon nanotubes (CNTs) and graphene derivatives. Such strong adsorbability, along with their high colloidal stability, makes NACs potentially suitable for remedy of aquifers contaminated with organic pollutants.
KW - Adsorption rate model
KW - Aromatic contaminants
KW - Freundlich equilibrium isotherm
KW - Groundwater remediation
KW - NACs
KW - Nanosized carbonaceous adsorbents
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U2 - 10.1016/j.cej.2017.06.183
DO - 10.1016/j.cej.2017.06.183
M3 - Article
AN - SCOPUS:85030451983
SN - 1385-8947
VL - 327
SP - 941
EP - 952
JO - Chemical Engineering Journal
JF - Chemical Engineering Journal
ER -