Alkane carbonylation photocatalyzed by aromatic ketones under high CO pressure

William T. Boese; Alan S. Goldman

doi:10.1016/0040-4039(92)88155-X

Alkane carbonylation photocatalyzed by aromatic ketones under high CO pressure

William T. Boese, Alan S. Goldman

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Aromatic ketones photocatalyze the carbonylation of alkanes to the corresponding aldehydes at room temperature under high CO pressures (20 - 80 atm). In the presence of CCl₄, cyclohexanecarbonylchloride is formed from cyclohexane; this reaction was used to determine the rate of addition of cyclohexyl radical to CO.

Original language	English (US)
Pages (from-to)	2119-2122
Number of pages	4
Journal	Tetrahedron Letters
Volume	33
Issue number	16
DOIs	https://doi.org/10.1016/0040-4039(92)88155-X
State	Published - Apr 14 1992

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(92)88155-X

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title = "Alkane carbonylation photocatalyzed by aromatic ketones under high CO pressure",

abstract = "Aromatic ketones photocatalyze the carbonylation of alkanes to the corresponding aldehydes at room temperature under high CO pressures (20 - 80 atm). In the presence of CCl4, cyclohexanecarbonylchloride is formed from cyclohexane; this reaction was used to determine the rate of addition of cyclohexyl radical to CO.",

author = "Boese, {William T.} and Goldman, {Alan S.}",

year = "1992",

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doi = "10.1016/0040-4039(92)88155-X",

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T1 - Alkane carbonylation photocatalyzed by aromatic ketones under high CO pressure

AU - Boese, William T.

AU - Goldman, Alan S.

PY - 1992/4/14

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N2 - Aromatic ketones photocatalyze the carbonylation of alkanes to the corresponding aldehydes at room temperature under high CO pressures (20 - 80 atm). In the presence of CCl4, cyclohexanecarbonylchloride is formed from cyclohexane; this reaction was used to determine the rate of addition of cyclohexyl radical to CO.

AB - Aromatic ketones photocatalyze the carbonylation of alkanes to the corresponding aldehydes at room temperature under high CO pressures (20 - 80 atm). In the presence of CCl4, cyclohexanecarbonylchloride is formed from cyclohexane; this reaction was used to determine the rate of addition of cyclohexyl radical to CO.

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M3 - Article

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VL - 33

SP - 2119

EP - 2122

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 16

ER -

Alkane carbonylation photocatalyzed by aromatic ketones under high CO pressure

Abstract

All Science Journal Classification (ASJC) codes

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