An Efficient Screen for Determining Solid-State Hydrogen-Bonding Patterns in Carboxylic Acids

Peggy A. Vanderhoff, Roger A. Lalancette, Hugh W. Thompson

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Simple crystalline keto carboxylic acids adopt hydrogen-bonding modes that are either intra- or inter-molecular, with the latter, far larger, class including carboxyl dimers and carboxyl-to-ketone catemers; it is demonstrated that symmetry-based differences between solid-state infrared and Raman spectra may be reliably used to differentiate those with dimeric H-bonding from those with noncentrosymmetric H-bonding patterns.

Original languageEnglish (US)
Pages (from-to)1696-1698
Number of pages3
JournalJournal of Organic Chemistry
Volume55
Issue number6
DOIs
StatePublished - Jan 1 1990

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Carboxylic Acids
Hydrogen bonds
Ketones
Dimers
Raman scattering
Crystalline materials
Infrared radiation

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

Cite this

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An Efficient Screen for Determining Solid-State Hydrogen-Bonding Patterns in Carboxylic Acids. / Vanderhoff, Peggy A.; Lalancette, Roger A.; Thompson, Hugh W.

In: Journal of Organic Chemistry, Vol. 55, No. 6, 01.01.1990, p. 1696-1698.

Research output: Contribution to journalArticle

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