An unexpected and unusual V(5+)10 cluster containing oxygen bridges as well as six bidentate acetylacetonates

Evrim Arslan; Roger A. Lalancette; Ivan Bernal

doi:10.1007/s11224-020-01521-z

An unexpected and unusual V(5+)₁₀ cluster containing oxygen bridges as well as six bidentate acetylacetonates

Evrim Arslan, Roger A. Lalancette, Ivan Bernal

Rutgers Newark, Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A cluster of 10 vanadium (5+) atoms bridged by 22 oxygen atoms and having six of the vanadiums around the periphery each bound to a single bidentate acetylacetone is described. This material has no unpaired electrons since V(5+) is 3d^o.

Original language	English (US)
Pages (from-to)	1217-1222
Number of pages	6
Journal	Structural Chemistry
Volume	31
Issue number	3
DOIs	https://doi.org/10.1007/s11224-020-01521-z
State	Published - Jun 1 2020

All Science Journal Classification (ASJC) codes

Condensed Matter Physics
Physical and Theoretical Chemistry

Keywords

Black crystals
Central oxygen surrounded by tetrahedral vanadiums
Decavanadium cluster
Toluene channels
V(5+) cations

Access to Document

10.1007/s11224-020-01521-z

Cite this

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title = "An unexpected and unusual V(5+)10 cluster containing oxygen bridges as well as six bidentate acetylacetonates",

abstract = "A cluster of 10 vanadium (5+) atoms bridged by 22 oxygen atoms and having six of the vanadiums around the periphery each bound to a single bidentate acetylacetone is described. This material has no unpaired electrons since V(5+) is 3do.",

keywords = "Black crystals, Central oxygen surrounded by tetrahedral vanadiums, Decavanadium cluster, Toluene channels, V(5+) cations",

author = "Evrim Arslan and Lalancette, {Roger A.} and Ivan Bernal",

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AU - Arslan, Evrim

AU - Lalancette, Roger A.

AU - Bernal, Ivan

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Y1 - 2020/6/1

N2 - A cluster of 10 vanadium (5+) atoms bridged by 22 oxygen atoms and having six of the vanadiums around the periphery each bound to a single bidentate acetylacetone is described. This material has no unpaired electrons since V(5+) is 3do.

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KW - Central oxygen surrounded by tetrahedral vanadiums

KW - Decavanadium cluster

KW - Toluene channels

KW - V(5+) cations

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