Analytical integral equation theory for a restricted primitive model of polyelectrolytes and counterions within the mean spherical approximation. II. Radial distribution functions

N. Von Solms; Y. C. Chiew

doi:10.1063/1.1539842

Analytical integral equation theory for a restricted primitive model of polyelectrolytes and counterions within the mean spherical approximation. II. Radial distribution functions

N. Von Solms, Y. C. Chiew

School of Engineering, Chemical & Biochemical Engineering

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

The mean spherical approximation for the thermodynamic properties and radial distribution functions of polyelectrolytes and counterions in solutions was solved analytically. The osmotic pressure predicted by the theory agreed well with available experimental results. Plots of radial distribution function vs separation for the three types of interactions (counterion-counterion, counterion-chain, and chain-chain) agree well with simulation data at high to moderate density.

Original language	English (US)
Pages (from-to)	4321-4330
Number of pages	10
Journal	Journal of Chemical Physics
Volume	118
Issue number	9
DOIs	https://doi.org/10.1063/1.1539842
State	Published - Mar 1 2003

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1063/1.1539842

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abstract = "The mean spherical approximation for the thermodynamic properties and radial distribution functions of polyelectrolytes and counterions in solutions was solved analytically. The osmotic pressure predicted by the theory agreed well with available experimental results. Plots of radial distribution function vs separation for the three types of interactions (counterion-counterion, counterion-chain, and chain-chain) agree well with simulation data at high to moderate density.",

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N2 - The mean spherical approximation for the thermodynamic properties and radial distribution functions of polyelectrolytes and counterions in solutions was solved analytically. The osmotic pressure predicted by the theory agreed well with available experimental results. Plots of radial distribution function vs separation for the three types of interactions (counterion-counterion, counterion-chain, and chain-chain) agree well with simulation data at high to moderate density.

AB - The mean spherical approximation for the thermodynamic properties and radial distribution functions of polyelectrolytes and counterions in solutions was solved analytically. The osmotic pressure predicted by the theory agreed well with available experimental results. Plots of radial distribution function vs separation for the three types of interactions (counterion-counterion, counterion-chain, and chain-chain) agree well with simulation data at high to moderate density.

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Analytical integral equation theory for a restricted primitive model of polyelectrolytes and counterions within the mean spherical approximation. II. Radial distribution functions

Abstract

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