Approximate kinetic theory of hard-sphere fluids near equilibrium. I. Formal theory

P. Resibois, Joel L. Lebowitz

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50 Scopus citations

Abstract

We propose a kinetic theory of hard-sphere fluids which systematically generalizes the Enskog equation by taking successively into account binary, ternary,... dynamic correlations in a system close to equilibrium. The first approximation, beyond Enskog, is displayed explicitly; it reproduces most of the results previously established in limiting cases (short-and long-time behavior, low-density expansions) and appears to give a good description of hard-sphere dynamics for all times and all densities. This explicit study will be presented in another publication.

Original languageEnglish (US)
Pages (from-to)483-516
Number of pages34
JournalJournal of Statistical Physics
Volume12
Issue number6
DOIs
StatePublished - Jun 1 1975
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Statistical and Nonlinear Physics
  • Mathematical Physics

Keywords

  • Kinetic theory
  • hard-sphere fluids
  • short- and long-time behavior
  • time-dependent correlation functions

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