Building a robust 3D Ca-MOF by a new square Ca4O SBU for purification of natural gas

Falu Hu; Zhengyi Di; Mingyan Wu; Jing Li

doi:10.1039/d0dt00943a

Building a robust 3D Ca-MOF by a new square Ca₄O SBU for purification of natural gas

Falu Hu, Zhengyi Di, Mingyan Wu, Jing Li

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

For the first time, a new square Ca4O SBU is introduced into a 3D Ca-MOF, ([MeNH2]2[Ca4O(MTB)2(EtOH)4])·(solvent)n (1), to generate a (4,8)-connected flu-topology structure. Compound 1 exhibits selective adsorption of C3 and C2 hydrocarbons and CO2 over CH4 with especially high IAST selectivities for C3 hydrocarbons over CH4 (at 15/85 and 50/50 ratio) at 298K and 1 bar.

Original language	English (US)
Pages (from-to)	8836-8840
Number of pages	5
Journal	Dalton Transactions
Volume	49
Issue number	26
DOIs	https://doi.org/10.1039/d0dt00943a
State	Published - Jul 14 2020

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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abstract = "For the first time, a new square Ca4O SBU is introduced into a 3D Ca-MOF, ([MeNH2]2[Ca4O(MTB)2(EtOH)4])·(solvent)n (1), to generate a (4,8)-connected flu-topology structure. Compound 1 exhibits selective adsorption of C3 and C2 hydrocarbons and CO2 over CH4 with especially high IAST selectivities for C3 hydrocarbons over CH4 (at 15/85 and 50/50 ratio) at 298K and 1 bar.",

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AU - Wu, Mingyan

AU - Li, Jing

PY - 2020/7/14

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AB - For the first time, a new square Ca4O SBU is introduced into a 3D Ca-MOF, ([MeNH2]2[Ca4O(MTB)2(EtOH)4])·(solvent)n (1), to generate a (4,8)-connected flu-topology structure. Compound 1 exhibits selective adsorption of C3 and C2 hydrocarbons and CO2 over CH4 with especially high IAST selectivities for C3 hydrocarbons over CH4 (at 15/85 and 50/50 ratio) at 298K and 1 bar.

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Building a robust 3D Ca-MOF by a new square Ca₄O SBU for purification of natural gas

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