Ce valence variation in intermetallic alloys: LIII absorption spectroscopy results

M. Croft; R. Neifeld; C. U. Segre; S. Raaen; R. D. Parks

doi:10.1103/PhysRevB.30.4164

Ce valence variation in intermetallic alloys: LIII absorption spectroscopy results

M. Croft, R. Neifeld, C. U. Segre, S. Raaen, R. D. Parks

School of Arts and Sciences, New High Energy Theory Center

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Abstract

LIII absorption spectroscopy measurements, using synchrotron radiation on the Ce1-xRxPd3, R=La3+, Y3+, Th4+, and U and the Ce1-xScxAl2 alloy systems are presented. The Ce valence variation from the LIII spectra analysis is correlated with the lattice-parameter variations in the alloys. The roles of the volume and valence of the substitutes in determining the Ce valence state are discussed. The results are discussed in terms of hybridization and current electronic theory.

Original language	English (US)
Pages (from-to)	4164-4169
Number of pages	6
Journal	Physical Review B
Volume	30
Issue number	8
DOIs	https://doi.org/10.1103/PhysRevB.30.4164
State	Published - 1984

All Science Journal Classification (ASJC) codes

Condensed Matter Physics

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10.1103/PhysRevB.30.4164

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title = "Ce valence variation in intermetallic alloys: LIII absorption spectroscopy results",

abstract = "LIII absorption spectroscopy measurements, using synchrotron radiation on the Ce1-xRxPd3, R=La3+, Y3+, Th4+, and U and the Ce1-xScxAl2 alloy systems are presented. The Ce valence variation from the LIII spectra analysis is correlated with the lattice-parameter variations in the alloys. The roles of the volume and valence of the substitutes in determining the Ce valence state are discussed. The results are discussed in terms of hybridization and current electronic theory.",

author = "M. Croft and R. Neifeld and Segre, \{C. U.\} and S. Raaen and Parks, \{R. D.\}",

year = "1984",

doi = "10.1103/PhysRevB.30.4164",

language = "English (US)",

volume = "30",

pages = "4164--4169",

journal = "Physical Review B",

issn = "0163-1829",

publisher = "American Institute of Physics",

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T1 - Ce valence variation in intermetallic alloys

T2 - LIII absorption spectroscopy results

AU - Croft, M.

AU - Neifeld, R.

AU - Segre, C. U.

AU - Raaen, S.

AU - Parks, R. D.

PY - 1984

Y1 - 1984

N2 - LIII absorption spectroscopy measurements, using synchrotron radiation on the Ce1-xRxPd3, R=La3+, Y3+, Th4+, and U and the Ce1-xScxAl2 alloy systems are presented. The Ce valence variation from the LIII spectra analysis is correlated with the lattice-parameter variations in the alloys. The roles of the volume and valence of the substitutes in determining the Ce valence state are discussed. The results are discussed in terms of hybridization and current electronic theory.

AB - LIII absorption spectroscopy measurements, using synchrotron radiation on the Ce1-xRxPd3, R=La3+, Y3+, Th4+, and U and the Ce1-xScxAl2 alloy systems are presented. The Ce valence variation from the LIII spectra analysis is correlated with the lattice-parameter variations in the alloys. The roles of the volume and valence of the substitutes in determining the Ce valence state are discussed. The results are discussed in terms of hybridization and current electronic theory.

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DO - 10.1103/PhysRevB.30.4164

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JO - Physical Review B

JF - Physical Review B

IS - 8

ER -

Ce valence variation in intermetallic alloys: LIII absorption spectroscopy results

Abstract

All Science Journal Classification (ASJC) codes

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