Chemistry and properties of cycloheptatetraene in the inner phase of a hemicarcerand

Keyphrases

• 1H NMR Studies 20%
• Acetal 40%
• Activation Free Energy 20%
• Activation Parameters 20%
• Benzene 20%
• Bulk Solvent 20%
• Butane 60%
• C-H Bond 20%
• Carbenes 20%
• Carbon Dioxide 20%
• Cavitands 40%
• Decarboxylation 20%
• Deuteration 20%
• Distance Ratio 20%
• Enantiomerization Barriers 20%
• Enthalpy-entropy Compensation 20%
• H1-H2 20%
• Hemicarcerands 100%
• Isopropylidene 20%
• Isotope Effect 20%
• Limited Time 20%
• Linker Group 60%
• Low Temperature 40%
• Lower Limit 20%
• NOE Experiments 20%
• Oxygen Addition 20%
• Photolysis 60%
• Proton 20%
• Reaction Coordinate 20%
• Ring Expansion 20%
• Room Temperature 20%
• Singlet 20%
• Solvent Dependence 20%
• Solvent Reorganization 20%
• Total Yield 20%
• Trienes 20%
• Twisted Structure 20%
• Variable Temperature 20%

Chemistry

• 1H NMR Spectroscopy 33%
• Acetal 66%
• Ambient Reaction Temperature 33%
• Carbene 33%
• Carbon Dioxide 33%
• Cavitand 66%
• Chemistry 100%
• Decarboxylation 33%
• Diastereomer 33%
• Enthalpy 33%
• Free Energy of Activation 33%
• Isotope Effect 33%
• Nuclear Overhauser Enhanced Spectroscopy 33%
• Photolysis 100%
• Ring Expansion 33%