Chromophore-Based Luminescent Metal-Organic Frameworks as Lighting Phosphors

William P. Lustig, Fangming Wang, Simon J. Teat, Zhichao Hu, Qihan Gong, Jing Li

Research output: Contribution to journalArticlepeer-review

57 Scopus citations

Abstract

Energy-efficient solid-state-lighting (SSL) technologies are rapidly developing, but the lack of stable, high-performance rare-earth free phosphors may impede the growth of the SSL market. One possible alternative is organic phosphor materials, but these can suffer from lower quantum yields and thermal instability compared to rare-earth phosphors. However, if luminescent organic chromophores can be built into a rigid metal-organic framework, their quantum yields and thermal stability can be greatly improved. This Forum Article discusses the design of a group of such chromophore-based luminescent metal-organic frameworks with exceptionally high performance and rational control of the important parameters that influence their emission properties, including electronic structures of chromophore, coligands, metal ions, and guest molecules.

Original languageEnglish (US)
Pages (from-to)7250-7256
Number of pages7
JournalInorganic Chemistry
Volume55
Issue number15
DOIs
StatePublished - Aug 1 2016

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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