(±)-cis-10-Carboxymethyl-2-decalone: Catemeric hydrogen bonding in an ε-keto acid

Daniel Zewge; Andrew P.J. Brunskill; Roger A. Lalancette; Hugh W. Thompson

doi:10.1107/S0108270198007495

(±)-cis-10-Carboxymethyl-2-decalone: Catemeric hydrogen bonding in an ε-keto acid

Daniel Zewge, Andrew P.J. Brunskill, Roger A. Lalancette, Hugh W. Thompson

Rutgers Newark, Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

The crystal structure of the title compound, (±)-cis-2-oxoperhydronaphthalene-4a-acetic acid, C₁₂H₁₈O₃, involves hydrogen-bonding catemers. Hydrogen bonds progress from the carboxyl group of one molecule to the ketone group of a translationally related neighbor [O⋯O 2.715 (3) Å]. Eight parallel hydrogen-bonding chains proceed in the a direction through the chosen cell. Two C=O⋯H-C close contacts were found, involving the acid carbonyl group.

Original language	English (US)
Pages (from-to)	1651-1653
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	11
DOIs	https://doi.org/10.1107/S0108270198007495
State	Published - Nov 15 1998

All Science Journal Classification (ASJC) codes

Biochemistry, Genetics and Molecular Biology(all)

Access to Document

10.1107/S0108270198007495

Fingerprint Dive into the research topics of '(±)-cis-10-Carboxymethyl-2-decalone: Catemeric hydrogen bonding in an ε-keto acid'. Together they form a unique fingerprint.

Cite this

@article{73d3549e8c91482aba4cf65e039b5aaa,

title = "(±)-cis-10-Carboxymethyl-2-decalone: Catemeric hydrogen bonding in an ε-keto acid",

abstract = "The crystal structure of the title compound, (±)-cis-2-oxoperhydronaphthalene-4a-acetic acid, C12H18O3, involves hydrogen-bonding catemers. Hydrogen bonds progress from the carboxyl group of one molecule to the ketone group of a translationally related neighbor [O⋯O 2.715 (3) {\AA}]. Eight parallel hydrogen-bonding chains proceed in the a direction through the chosen cell. Two C=O⋯H-C close contacts were found, involving the acid carbonyl group.",

author = "Daniel Zewge and Brunskill, {Andrew P.J.} and Lalancette, {Roger A.} and Thompson, {Hugh W.}",

year = "1998",

month = nov,

day = "15",

doi = "10.1107/S0108270198007495",

language = "English (US)",

volume = "54",

pages = "1651--1653",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "11",

}

TY - JOUR

T1 - (±)-cis-10-Carboxymethyl-2-decalone

T2 - Catemeric hydrogen bonding in an ε-keto acid

AU - Zewge, Daniel

AU - Brunskill, Andrew P.J.

AU - Lalancette, Roger A.

AU - Thompson, Hugh W.

PY - 1998/11/15

Y1 - 1998/11/15

N2 - The crystal structure of the title compound, (±)-cis-2-oxoperhydronaphthalene-4a-acetic acid, C12H18O3, involves hydrogen-bonding catemers. Hydrogen bonds progress from the carboxyl group of one molecule to the ketone group of a translationally related neighbor [O⋯O 2.715 (3) Å]. Eight parallel hydrogen-bonding chains proceed in the a direction through the chosen cell. Two C=O⋯H-C close contacts were found, involving the acid carbonyl group.

AB - The crystal structure of the title compound, (±)-cis-2-oxoperhydronaphthalene-4a-acetic acid, C12H18O3, involves hydrogen-bonding catemers. Hydrogen bonds progress from the carboxyl group of one molecule to the ketone group of a translationally related neighbor [O⋯O 2.715 (3) Å]. Eight parallel hydrogen-bonding chains proceed in the a direction through the chosen cell. Two C=O⋯H-C close contacts were found, involving the acid carbonyl group.

UR - http://www.scopus.com/inward/record.url?scp=0012660533&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0012660533&partnerID=8YFLogxK

U2 - 10.1107/S0108270198007495

DO - 10.1107/S0108270198007495

M3 - Article

AN - SCOPUS:0012660533

VL - 54

SP - 1651

EP - 1653

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 11

ER -