Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks

Haohan Wu; Qihan Gong; David H. Olson; Jing Li

doi:10.1021/cr200216x

Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks

Haohan Wu, Qihan Gong, David H. Olson, Jing Li

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Review article › peer-review

980 Scopus citations

Abstract

Commensurate adsorption of hydrocarbons and alcohols in microporous metal-organic frameworks (MOF) is studied. Diffusion studies of hydrocarbons in microporous MOF materials represent a new topic in adsorption related research. Transport properties of guest molecules are investigated by measuring their transport diffusivity and surface permeability employing state-of-the-art and high temporal and spatial resolution IR microimaging and interference (IF) microscopy. The normal C2-C4 alcohols is found to exhibit commensurate adsorption in RPM3-Zn near room temperature. RPM4-Zn takes up a significantly less amount of benzene and o-xylene compared to RPM3-Zn. Adsorption of styrene in MIL-47 represents another very interesting case. With a CdC double bond in place of a C double bond C single bond in EB, styrene is longer and more rigid than EB.

Original language	English (US)
Pages (from-to)	836-868
Number of pages	33
Journal	Chemical Reviews
Volume	112
Issue number	2
DOIs	https://doi.org/10.1021/cr200216x
State	Published - Feb 8 2012

All Science Journal Classification (ASJC) codes

General Chemistry

Access to Document

10.1021/cr200216x

Cite this

@article{050e5773d7454976a3e369d884a0ef0d,

title = "Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks",

abstract = "Commensurate adsorption of hydrocarbons and alcohols in microporous metal-organic frameworks (MOF) is studied. Diffusion studies of hydrocarbons in microporous MOF materials represent a new topic in adsorption related research. Transport properties of guest molecules are investigated by measuring their transport diffusivity and surface permeability employing state-of-the-art and high temporal and spatial resolution IR microimaging and interference (IF) microscopy. The normal C2-C4 alcohols is found to exhibit commensurate adsorption in RPM3-Zn near room temperature. RPM4-Zn takes up a significantly less amount of benzene and o-xylene compared to RPM3-Zn. Adsorption of styrene in MIL-47 represents another very interesting case. With a CdC double bond in place of a C double bond C single bond in EB, styrene is longer and more rigid than EB.",

author = "Haohan Wu and Qihan Gong and Olson, {David H.} and Jing Li",

year = "2012",

month = feb,

day = "8",

doi = "10.1021/cr200216x",

language = "English (US)",

volume = "112",

pages = "836--868",

journal = "Chemical Reviews",

issn = "0009-2665",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks

AU - Wu, Haohan

AU - Gong, Qihan

AU - Olson, David H.

AU - Li, Jing

PY - 2012/2/8

Y1 - 2012/2/8

N2 - Commensurate adsorption of hydrocarbons and alcohols in microporous metal-organic frameworks (MOF) is studied. Diffusion studies of hydrocarbons in microporous MOF materials represent a new topic in adsorption related research. Transport properties of guest molecules are investigated by measuring their transport diffusivity and surface permeability employing state-of-the-art and high temporal and spatial resolution IR microimaging and interference (IF) microscopy. The normal C2-C4 alcohols is found to exhibit commensurate adsorption in RPM3-Zn near room temperature. RPM4-Zn takes up a significantly less amount of benzene and o-xylene compared to RPM3-Zn. Adsorption of styrene in MIL-47 represents another very interesting case. With a CdC double bond in place of a C double bond C single bond in EB, styrene is longer and more rigid than EB.

AB - Commensurate adsorption of hydrocarbons and alcohols in microporous metal-organic frameworks (MOF) is studied. Diffusion studies of hydrocarbons in microporous MOF materials represent a new topic in adsorption related research. Transport properties of guest molecules are investigated by measuring their transport diffusivity and surface permeability employing state-of-the-art and high temporal and spatial resolution IR microimaging and interference (IF) microscopy. The normal C2-C4 alcohols is found to exhibit commensurate adsorption in RPM3-Zn near room temperature. RPM4-Zn takes up a significantly less amount of benzene and o-xylene compared to RPM3-Zn. Adsorption of styrene in MIL-47 represents another very interesting case. With a CdC double bond in place of a C double bond C single bond in EB, styrene is longer and more rigid than EB.

UR - http://www.scopus.com/inward/record.url?scp=84863011315&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84863011315&partnerID=8YFLogxK

U2 - 10.1021/cr200216x

DO - 10.1021/cr200216x

M3 - Review article

C2 - 22257090

AN - SCOPUS:84863011315

SN - 0009-2665

VL - 112

SP - 836

EP - 868

JO - Chemical Reviews

JF - Chemical Reviews

IS - 2

ER -

Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this