Complete assignment of 19F, 1H and 13C NMR spectra of monomers and precursors towards bridge trifluoromethylated poly(p-phenylenevinylene)

Alex J. Roche

doi:10.1002/mrc.1425

Complete assignment of ¹⁹F, ¹H and ¹³C NMR spectra of monomers and precursors towards bridge trifluoromethylated poly(p-phenylenevinylene)

Alex J. Roche

Rutgers Camden, Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The complete assignment of ¹⁹F, ¹H and ¹³C NMR spectra of 11 trifluoromethylated and four bistrifluoromethylated monomers for bridge trifluoromethylated poly(p-phenylenevinylene) is described. The combination of one-dimensional ¹⁹F, ¹H and ¹³C spectra, long-range fluorine couplings and the two-dimensional techniques of direct and long-range HETCOR (J = 140 and 8 Hz) permitted full resonance assignment.

Original language	English (US)
Pages (from-to)	944-949
Number of pages	6
Journal	Magnetic Resonance in Chemistry
Volume	42
Issue number	11
DOIs	https://doi.org/10.1002/mrc.1425
State	Published - Nov 2004

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science

Keywords

2D NMR
C NMR
Conjugated polymers
Diastereomers
F NMR
H NMR
HETCOR
NMR
Poly(p-phenylenevinylene)
Precursor polymers
Trifluoromethyl

Access to Document

10.1002/mrc.1425

Cite this

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title = "Complete assignment of 19F, 1H and 13C NMR spectra of monomers and precursors towards bridge trifluoromethylated poly(p-phenylenevinylene)",

abstract = "The complete assignment of 19F, 1H and 13C NMR spectra of 11 trifluoromethylated and four bistrifluoromethylated monomers for bridge trifluoromethylated poly(p-phenylenevinylene) is described. The combination of one-dimensional 19F, 1H and 13C spectra, long-range fluorine couplings and the two-dimensional techniques of direct and long-range HETCOR (J = 140 and 8 Hz) permitted full resonance assignment.",

keywords = "2D NMR, C NMR, Conjugated polymers, Diastereomers, F NMR, H NMR, HETCOR, NMR, Poly(p-phenylenevinylene), Precursor polymers, Trifluoromethyl",

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year = "2004",

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T1 - Complete assignment of 19F, 1H and 13C NMR spectra of monomers and precursors towards bridge trifluoromethylated poly(p-phenylenevinylene)

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N2 - The complete assignment of 19F, 1H and 13C NMR spectra of 11 trifluoromethylated and four bistrifluoromethylated monomers for bridge trifluoromethylated poly(p-phenylenevinylene) is described. The combination of one-dimensional 19F, 1H and 13C spectra, long-range fluorine couplings and the two-dimensional techniques of direct and long-range HETCOR (J = 140 and 8 Hz) permitted full resonance assignment.

AB - The complete assignment of 19F, 1H and 13C NMR spectra of 11 trifluoromethylated and four bistrifluoromethylated monomers for bridge trifluoromethylated poly(p-phenylenevinylene) is described. The combination of one-dimensional 19F, 1H and 13C spectra, long-range fluorine couplings and the two-dimensional techniques of direct and long-range HETCOR (J = 140 and 8 Hz) permitted full resonance assignment.

KW - 2D NMR

KW - C NMR

KW - Conjugated polymers

KW - Diastereomers

KW - F NMR

KW - H NMR

KW - HETCOR

KW - NMR

KW - Poly(p-phenylenevinylene)

KW - Precursor polymers

KW - Trifluoromethyl

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DO - 10.1002/mrc.1425

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SN - 0749-1581

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JO - Magnetic Resonance in Chemistry

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