Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts

Abhishek Anan; Rajyalakshmi Vathyam; Krishna K. Sharma; Tewodros Asefa

doi:10.1007/s10562-008-9595-1

Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts

Abhishek Anan, Rajyalakshmi Vathyam, Krishna K. Sharma, Tewodros Asefa

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

A synthetic method for controlling the Henry reaction products from nitrostyrene to nitroalcohol in heterogeneous catalysis by a simple change of the catalytic sites in organoamine-functionalized mesoporous catalysts is reported. The synthesis resulted in either β-nitrostyrene or β-nitroalcohol by simple change of the types of amine functional groups in the amine-functionalized mesoporous catalysts from primary amines into secondary or tertiary.

Original language	English (US)
Pages (from-to)	142-148
Number of pages	7
Journal	Catalysis Letters
Volume	126
Issue number	1-2
DOIs	https://doi.org/10.1007/s10562-008-9595-1
State	Published - Nov 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Keywords

Amine-functionalized mesoporous materials
Henry reaction
Nitroalcohol
Nitroaldol condensation
Nitrostyrene

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10.1007/s10562-008-9595-1

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title = "Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts",

abstract = "A synthetic method for controlling the Henry reaction products from nitrostyrene to nitroalcohol in heterogeneous catalysis by a simple change of the catalytic sites in organoamine-functionalized mesoporous catalysts is reported. The synthesis resulted in either β-nitrostyrene or β-nitroalcohol by simple change of the types of amine functional groups in the amine-functionalized mesoporous catalysts from primary amines into secondary or tertiary.",

keywords = "Amine-functionalized mesoporous materials, Henry reaction, Nitroalcohol, Nitroaldol condensation, Nitrostyrene",

author = "Abhishek Anan and Rajyalakshmi Vathyam and Sharma, {Krishna K.} and Tewodros Asefa",

note = "Funding Information: Acknowledgments We gratefully acknowledge the financial support by the US National Science Foundation (NSF), CAREER Grant, NSF CHE-0645348 for this work. We wish to thank Cole Duncan for valuable discussion.",

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doi = "10.1007/s10562-008-9595-1",

language = "English (US)",

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T2 - Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts

AU - Anan, Abhishek

AU - Vathyam, Rajyalakshmi

AU - Sharma, Krishna K.

AU - Asefa, Tewodros

N1 - Funding Information: Acknowledgments We gratefully acknowledge the financial support by the US National Science Foundation (NSF), CAREER Grant, NSF CHE-0645348 for this work. We wish to thank Cole Duncan for valuable discussion.

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N2 - A synthetic method for controlling the Henry reaction products from nitrostyrene to nitroalcohol in heterogeneous catalysis by a simple change of the catalytic sites in organoamine-functionalized mesoporous catalysts is reported. The synthesis resulted in either β-nitrostyrene or β-nitroalcohol by simple change of the types of amine functional groups in the amine-functionalized mesoporous catalysts from primary amines into secondary or tertiary.

AB - A synthetic method for controlling the Henry reaction products from nitrostyrene to nitroalcohol in heterogeneous catalysis by a simple change of the catalytic sites in organoamine-functionalized mesoporous catalysts is reported. The synthesis resulted in either β-nitrostyrene or β-nitroalcohol by simple change of the types of amine functional groups in the amine-functionalized mesoporous catalysts from primary amines into secondary or tertiary.

KW - Amine-functionalized mesoporous materials

KW - Henry reaction

KW - Nitroalcohol

KW - Nitroaldol condensation

KW - Nitrostyrene

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Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts

Abstract

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Keywords

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