Crystal and magnetic structure of the Ca3Mn2O 7 Ruddlesden-Popper phase: Neutron and synchrotron x-ray diffraction study

Maxim V. Lobanov; Martha Greenblatt; El'ad N. Caspi; James D. Jorgensen; Denis V. Sheptyakov; Brian H. Toby; Cristian E. Botez; Peter W. Stephens

doi:10.1088/0953-8984/16/29/023

Crystal and magnetic structure of the Ca₃Mn₂O ₇ Ruddlesden-Popper phase: Neutron and synchrotron x-ray diffraction study

Maxim V. Lobanov, Martha Greenblatt, El'ad N. Caspi, James D. Jorgensen, Denis V. Sheptyakov, Brian H. Toby, Cristian E. Botez, Peter W. Stephens

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

84 Scopus citations

Abstract

The crystallographic and magnetic structures of Ca₃Mn ₂O₇ Ruddlesden-Popper phase have been determined by a combination of neutron and synchrotron x-ray diffraction. Two-phase behaviour observed at room temperature is attributed to an incomplete structural phase transition. The magnetic structure was solved in the Cm′c2′₁ Shubnikov group with dominant G-type antiferromagnetic order in the perovskite bilayers. The temperature evolution of the structural and magnetic parameters is presented.

Original language	English (US)
Pages (from-to)	5339-5348
Number of pages	10
Journal	Journal of Physics Condensed Matter
Volume	16
Issue number	29
DOIs	https://doi.org/10.1088/0953-8984/16/29/023
State	Published - Jul 28 2004

All Science Journal Classification (ASJC) codes

General Materials Science
Condensed Matter Physics

Access to Document

10.1088/0953-8984/16/29/023

Cite this

@article{89b7618d32824a0fbf58839fc70ba45e,

title = "Crystal and magnetic structure of the Ca3Mn2O 7 Ruddlesden-Popper phase: Neutron and synchrotron x-ray diffraction study",

abstract = "The crystallographic and magnetic structures of Ca3Mn 2O7 Ruddlesden-Popper phase have been determined by a combination of neutron and synchrotron x-ray diffraction. Two-phase behaviour observed at room temperature is attributed to an incomplete structural phase transition. The magnetic structure was solved in the Cm′c2′1 Shubnikov group with dominant G-type antiferromagnetic order in the perovskite bilayers. The temperature evolution of the structural and magnetic parameters is presented.",

author = "Lobanov, {Maxim V.} and Martha Greenblatt and Caspi, {El'ad N.} and Jorgensen, {James D.} and Sheptyakov, {Denis V.} and Toby, {Brian H.} and Botez, {Cristian E.} and Stephens, {Peter W.}",

year = "2004",

month = jul,

day = "28",

doi = "10.1088/0953-8984/16/29/023",

language = "English (US)",

volume = "16",

pages = "5339--5348",

journal = "Journal of Physics Condensed Matter",

issn = "0953-8984",

publisher = "IOP Publishing Ltd.",

number = "29",

}

TY - JOUR

T1 - Crystal and magnetic structure of the Ca3Mn2O 7 Ruddlesden-Popper phase

T2 - Neutron and synchrotron x-ray diffraction study

AU - Lobanov, Maxim V.

AU - Greenblatt, Martha

AU - Caspi, El'ad N.

AU - Jorgensen, James D.

AU - Sheptyakov, Denis V.

AU - Toby, Brian H.

AU - Botez, Cristian E.

AU - Stephens, Peter W.

PY - 2004/7/28

Y1 - 2004/7/28

N2 - The crystallographic and magnetic structures of Ca3Mn 2O7 Ruddlesden-Popper phase have been determined by a combination of neutron and synchrotron x-ray diffraction. Two-phase behaviour observed at room temperature is attributed to an incomplete structural phase transition. The magnetic structure was solved in the Cm′c2′1 Shubnikov group with dominant G-type antiferromagnetic order in the perovskite bilayers. The temperature evolution of the structural and magnetic parameters is presented.

AB - The crystallographic and magnetic structures of Ca3Mn 2O7 Ruddlesden-Popper phase have been determined by a combination of neutron and synchrotron x-ray diffraction. Two-phase behaviour observed at room temperature is attributed to an incomplete structural phase transition. The magnetic structure was solved in the Cm′c2′1 Shubnikov group with dominant G-type antiferromagnetic order in the perovskite bilayers. The temperature evolution of the structural and magnetic parameters is presented.

UR - http://www.scopus.com/inward/record.url?scp=3342974733&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=3342974733&partnerID=8YFLogxK

U2 - 10.1088/0953-8984/16/29/023

DO - 10.1088/0953-8984/16/29/023

M3 - Article

AN - SCOPUS:3342974733

SN - 0953-8984

VL - 16

SP - 5339

EP - 5348

JO - Journal of Physics Condensed Matter

JF - Journal of Physics Condensed Matter

IS - 29

ER -

Crystal and magnetic structure of the Ca₃Mn₂O ₇ Ruddlesden-Popper phase: Neutron and synchrotron x-ray diffraction study

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this