Cuprophilic and π-stacking interactions in the formation of supramolecular stacks from dicoordinate organocopper complexes

Anand Sundararaman; Lev N. Zakharov; Arnold L. Rheingold; Frieder Jäkle

doi:10.1039/b417532h

Cuprophilic and π-stacking interactions in the formation of supramolecular stacks from dicoordinate organocopper complexes

Anand Sundararaman, Lev N. Zakharov, Arnold L. Rheingold, Frieder Jäkle

Rutgers Newark, Chemistry

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

The unsupported organocopper pyridine complexes C₆F ₅Cu(Py) (2) and [C₆F₅Cu]₂-bipy) (3) form supramolecular structures that are unprecedented in organocopper chemistry; one-dimensional chains of copper atoms with Cu⋯Cu distances of 2.8924(3) Åin the blue-luminescent complex 2 are likely associated with cuprophilic interactions, whereas multiple perfluoroarene-arene interactions dominate in the supramolecular assembly of 3.

Original language	English (US)
Pages (from-to)	1708-1710
Number of pages	3
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/b417532h
State	Published - Apr 7 2005

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Cuprophilic and π-stacking interactions in the formation of supramolecular stacks from dicoordinate organocopper complexes",

abstract = "The unsupported organocopper pyridine complexes C6F 5Cu(Py) (2) and [C6F5Cu]2-bipy) (3) form supramolecular structures that are unprecedented in organocopper chemistry; one-dimensional chains of copper atoms with Cu⋯Cu distances of 2.8924(3) {\AA}in the blue-luminescent complex 2 are likely associated with cuprophilic interactions, whereas multiple perfluoroarene-arene interactions dominate in the supramolecular assembly of 3.",

author = "Anand Sundararaman and Zakharov, {Lev N.} and Rheingold, {Arnold L.} and Frieder J{\"a}kle",

year = "2005",

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doi = "10.1039/b417532h",

language = "English (US)",

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journal = "Chemical Communications",

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AU - Sundararaman, Anand

AU - Zakharov, Lev N.

AU - Rheingold, Arnold L.

AU - Jäkle, Frieder

PY - 2005/4/7

Y1 - 2005/4/7

N2 - The unsupported organocopper pyridine complexes C6F 5Cu(Py) (2) and [C6F5Cu]2-bipy) (3) form supramolecular structures that are unprecedented in organocopper chemistry; one-dimensional chains of copper atoms with Cu⋯Cu distances of 2.8924(3) Åin the blue-luminescent complex 2 are likely associated with cuprophilic interactions, whereas multiple perfluoroarene-arene interactions dominate in the supramolecular assembly of 3.

AB - The unsupported organocopper pyridine complexes C6F 5Cu(Py) (2) and [C6F5Cu]2-bipy) (3) form supramolecular structures that are unprecedented in organocopper chemistry; one-dimensional chains of copper atoms with Cu⋯Cu distances of 2.8924(3) Åin the blue-luminescent complex 2 are likely associated with cuprophilic interactions, whereas multiple perfluoroarene-arene interactions dominate in the supramolecular assembly of 3.

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JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Cuprophilic and π-stacking interactions in the formation of supramolecular stacks from dicoordinate organocopper complexes

Abstract

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