DBTTF-TCNQ: A fractionally-charged organic salt with a mixed-stack crystalline motif

T. J. Kistenmacher; T. J. Emge; F. M. Wiygul; W. A. Bryden; J. S. Chappell; J. P. Stokes; L. Y. Chiang; D. O. Cowan; A. N. Bloch

doi:10.1016/0038-1098(81)90630-X

DBTTF-TCNQ: A fractionally-charged organic salt with a mixed-stack crystalline motif

T. J. Kistenmacher, T. J. Emge, F. M. Wiygul, W. A. Bryden, J. S. Chappell, J. P. Stokes, L. Y. Chiang, D. O. Cowan, A. N. Bloch

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

X-Ray diffraction measurements demonstrate that the organic charge-transfer salt formed from the donor(D) DBTTF and the acceptor(A) TCNQ exists as a mixed stack(...DADA...) crystalline array. From the donor and acceptor geometries and solid state infrared spectrum, an unusual charge transfer(for a ...DADA... motif) of 0.47e is derived. The Madelung contribution, -2.9 eV/DA pair, has been evaluated and found to be deficient relative to the cost of ionization of the components.

Original language	English (US)
Pages (from-to)	415-417
Number of pages	3
Journal	Solid State Communications
Volume	39
Issue number	3
DOIs	https://doi.org/10.1016/0038-1098(81)90630-X
State	Published - Jul 1981
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry
Condensed Matter Physics
Materials Chemistry

Access to Document

10.1016/0038-1098(81)90630-X

Cite this

@article{fbd367c71a214e028b2f57ddabbd0b00,

title = "DBTTF-TCNQ: A fractionally-charged organic salt with a mixed-stack crystalline motif",

abstract = "X-Ray diffraction measurements demonstrate that the organic charge-transfer salt formed from the donor(D) DBTTF and the acceptor(A) TCNQ exists as a mixed stack(...DADA...) crystalline array. From the donor and acceptor geometries and solid state infrared spectrum, an unusual charge transfer(for a ...DADA... motif) of 0.47e is derived. The Madelung contribution, -2.9 eV/DA pair, has been evaluated and found to be deficient relative to the cost of ionization of the components.",

author = "Kistenmacher, {T. J.} and Emge, {T. J.} and Wiygul, {F. M.} and Bryden, {W. A.} and Chappell, {J. S.} and Stokes, {J. P.} and Chiang, {L. Y.} and Cowan, {D. O.} and Bloch, {A. N.}",

year = "1981",

month = jul,

doi = "10.1016/0038-1098(81)90630-X",

language = "English (US)",

volume = "39",

pages = "415--417",

journal = "Solid State Communications",

issn = "0038-1098",

publisher = "Elsevier Ltd",

number = "3",

}

TY - JOUR

T1 - DBTTF-TCNQ

T2 - A fractionally-charged organic salt with a mixed-stack crystalline motif

AU - Kistenmacher, T. J.

AU - Emge, T. J.

AU - Wiygul, F. M.

AU - Bryden, W. A.

AU - Chappell, J. S.

AU - Stokes, J. P.

AU - Chiang, L. Y.

AU - Cowan, D. O.

AU - Bloch, A. N.

PY - 1981/7

Y1 - 1981/7

N2 - X-Ray diffraction measurements demonstrate that the organic charge-transfer salt formed from the donor(D) DBTTF and the acceptor(A) TCNQ exists as a mixed stack(...DADA...) crystalline array. From the donor and acceptor geometries and solid state infrared spectrum, an unusual charge transfer(for a ...DADA... motif) of 0.47e is derived. The Madelung contribution, -2.9 eV/DA pair, has been evaluated and found to be deficient relative to the cost of ionization of the components.

AB - X-Ray diffraction measurements demonstrate that the organic charge-transfer salt formed from the donor(D) DBTTF and the acceptor(A) TCNQ exists as a mixed stack(...DADA...) crystalline array. From the donor and acceptor geometries and solid state infrared spectrum, an unusual charge transfer(for a ...DADA... motif) of 0.47e is derived. The Madelung contribution, -2.9 eV/DA pair, has been evaluated and found to be deficient relative to the cost of ionization of the components.

UR - http://www.scopus.com/inward/record.url?scp=0019584474&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0019584474&partnerID=8YFLogxK

U2 - 10.1016/0038-1098(81)90630-X

DO - 10.1016/0038-1098(81)90630-X

M3 - Article

AN - SCOPUS:0019584474

SN - 0038-1098

VL - 39

SP - 415

EP - 417

JO - Solid State Communications

JF - Solid State Communications

IS - 3

ER -

DBTTF-TCNQ: A fractionally-charged organic salt with a mixed-stack crystalline motif

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this