Deformation and fracture of ionomeric blends. Sulfonated polystyrene ionomer/polystyrene

M. Bellinger, P. Jar, J. A. Sauer, M. Hara

Research output: Contribution to journalConference articlepeer-review

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Abstract

In this work, we have studied the deformation behavior of sulfonated polystyrene ionomer/polystyrene (PS) blends in order to understand the effect of a hard, ionomer-rich second phase on mechanical properties, especially on toughness of the glassy polymers. The micromorphology and deformation mechanisms of ionomer/PS blends were studied by transmission electron microscopy (TEM). Blend samples studied all show a phase-separated microstructure, and phase inversion occurs as the ionomer content increases. It is observed for ionomer/PS (10/90 and 30/70) blends that the rigid ionomer-rich, second phase particles generate many small crazes and that they also elongate substantially along the stress direction.

Original languageEnglish (US)
Pages (from-to)546-547
Number of pages2
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume31
Issue number1
StatePublished - Apr 1990
EventPapers Presented at the Boston, Massachusetts Meeting of ACS 1989 - Boston, MA, USA
Duration: Apr 22 1989Apr 27 1989

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics

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