Diferrocenophosphaborin: A Planar-Chiral, Redox-Active and Anion-Responsive Ambiphilic Ligand

Jiawei Chen, Didier A. Murillo Parra, Roger A. Lalancette, Frieder Jäkle

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

A new class of Janus-like ambiphilic ligands is introduced. The rigid diferrocene backbone in heterocycles 4-SnP and 4-BP creates an unprecedented chiral environment as demonstrated by multinuclear NMR and single-crystal X-ray studies. In addition, the ligands are redox-responsive and the Lewis acidic borane moiety in 4-BP can be exploited to further tune the properties: a clear decrease in the CO stretching frequency of a Vaska-type RhI complex 5-BP is observed upon addition of fluoride ions. Thus, the Lewis acid and Lewis base sites influence each other and their strength can be modulated by redox chemistry and anion binding.

Original languageEnglish (US)
Pages (from-to)10202-10205
Number of pages4
JournalAngewandte Chemie - International Edition
Volume54
Issue number35
DOIs
StatePublished - Aug 1 2015

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Keywords

  • Lewis acids
  • ambiphilic ligands
  • ferrocenes
  • planar chirality
  • redox activity

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