Dinitrogen complexes of pincer-ligated iridium

Rajshekhar Ghosh, Mira Kanzelberger, Thomas Emge, Gene Hall, Alan Goldman

Research output: Contribution to journalArticle

43 Scopus citations

Abstract

Precursors of the fragment (PCP)Ir have been previously reported to react with dinitrogen to give the bridging dinuclear complex [(PCP)Ir] 2(N 2) (2), which was crystallographically characterized. We report that under N 2 atmosphere the only observable nitrogen complex in solution is actually the terminal dinitrogen complex (PCP)Ir(N 2). The mono- and dinuclear species are in equilibrium; the dinuclear complex more readily crystallizes from solution.

Original languageEnglish (US)
Pages (from-to)5668-5671
Number of pages4
JournalOrganometallics
Volume25
Issue number23
DOIs
StatePublished - Nov 6 2006

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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