Dinitrogen complexes of pincer-ligated iridium

Rajshekhar Ghosh, Mira Kanzelberger, Thomas Emge, Gene Hall, Alan Goldman

Research output: Contribution to journalArticle

42 Citations (Scopus)

Abstract

Precursors of the fragment (PCP)Ir have been previously reported to react with dinitrogen to give the bridging dinuclear complex [(PCP)Ir] 2(N 2) (2), which was crystallographically characterized. We report that under N 2 atmosphere the only observable nitrogen complex in solution is actually the terminal dinitrogen complex (PCP)Ir(N 2). The mono- and dinuclear species are in equilibrium; the dinuclear complex more readily crystallizes from solution.

Original languageEnglish (US)
Pages (from-to)5668-5671
Number of pages4
JournalOrganometallics
Volume25
Issue number23
DOIs
StatePublished - Nov 6 2006

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Iridium
iridium
Nitrogen
fragments
nitrogen
atmospheres

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Ghosh, Rajshekhar ; Kanzelberger, Mira ; Emge, Thomas ; Hall, Gene ; Goldman, Alan. / Dinitrogen complexes of pincer-ligated iridium. In: Organometallics. 2006 ; Vol. 25, No. 23. pp. 5668-5671.
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Dinitrogen complexes of pincer-ligated iridium. / Ghosh, Rajshekhar; Kanzelberger, Mira; Emge, Thomas; Hall, Gene; Goldman, Alan.

In: Organometallics, Vol. 25, No. 23, 06.11.2006, p. 5668-5671.

Research output: Contribution to journalArticle

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