Discovery of Ultra-Crack-Resistant Oxide Glasses with Adaptive Networks

Kacper Januchta, Randall E. Youngman, Ashutosh Goel, Mathieu Bauchy, Stephan L. Logunov, Sylwester J. Rzoska, Michal Bockowski, Lars R. Jensen, Morten M. Smedskjaer

Research output: Contribution to journalArticle

42 Scopus citations


Despite their transformative role in our society, oxide glasses remain brittle. Although extrinsic postprocessing techniques can partially mitigate this drawback, they come with undesirable side effects. Alternatively, topological engineering offers an attractive option to enhance the intrinsic strength and damage resistance of glass. On the basis of this approach, we report here the discovery of a novel melt-quenched lithium aluminoborate glass featuring the highest crack resistance ever reported for a bulk oxide glass. Relying on combined mechanical and structural characterizations, we demonstrate that this unusual damage resistance originates from a significant self-adaptivity of the local atomic topology under stress, which, based on a selection of various oxide glasses, is shown to control crack resistance. This renders the lithium aluminoborate glass a promising candidate for engineering applications, such as ultrathin, yet ultrastrong, protective screens.

Original languageEnglish (US)
Pages (from-to)5865-5876
Number of pages12
JournalChemistry of Materials
Issue number14
StatePublished - Jul 25 2017


All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

Januchta, K., Youngman, R. E., Goel, A., Bauchy, M., Logunov, S. L., Rzoska, S. J., Bockowski, M., Jensen, L. R., & Smedskjaer, M. M. (2017). Discovery of Ultra-Crack-Resistant Oxide Glasses with Adaptive Networks. Chemistry of Materials, 29(14), 5865-5876.