Effect of dissolved LiCl on the ionic liquid–Au(111) electrical double layer structure

Robert Hayes; Natalia Borisenko; Brendan Corr; Grant B. Webber; Frank Endres; Rob Atkin

doi:10.1039/c2cc35737b

Effect of dissolved LiCl on the ionic liquid–Au(111) electrical double layer structure

Robert Hayes, Natalia Borisenko, Brendan Corr, Grant B. Webber, Frank Endres, Rob Atkin

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

The electrical double layer at ionic liquid (IL)–Au(111) interfaces is composed of alternating ion layers. Interfacial layering is markedly weaker when small amounts of LiCl are dissolved in the IL for all potential between −2.0 V and +2.0 V (vs. Pt). This means that models developed for pure IL electrical double layers may not be valid when solutes are present.

Original language	English (US)
Pages (from-to)	10246-10248
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	82
DOIs	https://doi.org/10.1039/c2cc35737b
State	Published - Sep 19 2012
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c2cc35737b

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abstract = "The electrical double layer at ionic liquid (IL)–Au(111) interfaces is composed of alternating ion layers. Interfacial layering is markedly weaker when small amounts of LiCl are dissolved in the IL for all potential between −2.0 V and +2.0 V (vs. Pt). This means that models developed for pure IL electrical double layers may not be valid when solutes are present.",

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AU - Hayes, Robert

AU - Borisenko, Natalia

AU - Corr, Brendan

AU - Webber, Grant B.

AU - Endres, Frank

AU - Atkin, Rob

PY - 2012/9/19

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AB - The electrical double layer at ionic liquid (IL)–Au(111) interfaces is composed of alternating ion layers. Interfacial layering is markedly weaker when small amounts of LiCl are dissolved in the IL for all potential between −2.0 V and +2.0 V (vs. Pt). This means that models developed for pure IL electrical double layers may not be valid when solutes are present.

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Effect of dissolved LiCl on the ionic liquid–Au(111) electrical double layer structure

Abstract

All Science Journal Classification (ASJC) codes

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