Effect of metal chlorides on glucose mutarotation and possible implications on humin formation

Pranav Ramesh, Athanasios Kritikos, George Tsilomelekis

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

An in situ Raman spectroscopic kinetic study of the glucose mutarotation reaction is presented herein. The effect of metal chlorides on the ease of the ring opening process is discussed. It is shown that SnCl 4 facilitates the mutarotation process towards the β-anomer extremely fast, while CrCl 3 appears to promote the formation of the α-anomer of glucose. The infrared spectra of humins prepared in different Lewis acids underscore the possibility of multiple reaction pathways.

Original languageEnglish (US)
Pages (from-to)273-277
Number of pages5
JournalReaction Chemistry and Engineering
Volume4
Issue number2
DOIs
StatePublished - Feb 1 2019

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry (miscellaneous)
  • Chemical Engineering (miscellaneous)
  • Process Chemistry and Technology
  • Fluid Flow and Transfer Processes

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