Effect of thickness of the intergranular film on fracture in Si 3N4

Shenghong Zhang, Stephen H. Garofalini

Research output: Contribution to journalArticlepeer-review

5 Scopus citations


Molecular dynamics computer simulations were used to study the fracture behavior of silica intergranular films (IGFs) between silicon nitride crystals as a function of film thickness. Results showed a significant increase in fracture stress with decreasing IGF thickness. IGFs that are 2 nm thick fracture similarly to bulk silica glass, while the 1 nm IGF fractured at a much higher value. The simulations show bond rupture and rearrangement of siloxane rings that coalescence to form larger rings, or "voids." The delineating difference in the systems is the significantly larger concentration of six-membered rings in the 1 nm IGF in comparison to the 2 nm IGF or bulk silica glass. The Si-O bond is more stable in six-membered rings than other ring sizes. Rupture is more catastrophic in the 1 nm IGF than the other systems where stress decays more slowly with strain.

Original languageEnglish (US)
Pages (from-to)147-151
Number of pages5
JournalJournal of the American Ceramic Society
Issue number1
StatePublished - Jan 2009

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

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