Electrochemical Science and Technology: Evaluation of the Kinetic Parameters of the Sodium Insertion in Sodium Molybdates by Impedance Spectroscopy

S. Colson; L. C. Klein

doi:10.1149/1.2221231

Electrochemical Science and Technology: Evaluation of the Kinetic Parameters of the Sodium Insertion in Sodium Molybdates by Impedance Spectroscopy

S. Colson, L. C. Klein

School of Engineering, Materials Science & Engineering

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The kinetics of the insertion of Na into the layered Na_xMo₂O₄, system upon charge and discharge has been studied by means of ac-complex impedance spectroscopy. The Nadiffusion coefficient values'deduced correlate well with the structural modifications occurring in these monoclinic molybdates upon Na intercalation, namely, change from trigonat prismatic coordination for low sodium content tooctahedral for higher content.

Original language	English (US)
Pages (from-to)	2359-2362
Number of pages	4
Journal	Journal of the Electrochemical Society
Volume	139
Issue number	9
DOIs	https://doi.org/10.1149/1.2221231
State	Published - Sep 1992

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films
Electrochemistry
Materials Chemistry

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title = "Electrochemical Science and Technology: Evaluation of the Kinetic Parameters of the Sodium Insertion in Sodium Molybdates by Impedance Spectroscopy",

abstract = "The kinetics of the insertion of Na into the layered NaxMo2O4, system upon charge and discharge has been studied by means of ac-complex impedance spectroscopy. The Nadiffusion coefficient values'deduced correlate well with the structural modifications occurring in these monoclinic molybdates upon Na intercalation, namely, change from trigonat prismatic coordination for low sodium content tooctahedral for higher content.",

author = "S. Colson and Klein, {L. C.}",

year = "1992",

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N2 - The kinetics of the insertion of Na into the layered NaxMo2O4, system upon charge and discharge has been studied by means of ac-complex impedance spectroscopy. The Nadiffusion coefficient values'deduced correlate well with the structural modifications occurring in these monoclinic molybdates upon Na intercalation, namely, change from trigonat prismatic coordination for low sodium content tooctahedral for higher content.

AB - The kinetics of the insertion of Na into the layered NaxMo2O4, system upon charge and discharge has been studied by means of ac-complex impedance spectroscopy. The Nadiffusion coefficient values'deduced correlate well with the structural modifications occurring in these monoclinic molybdates upon Na intercalation, namely, change from trigonat prismatic coordination for low sodium content tooctahedral for higher content.

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Electrochemical Science and Technology: Evaluation of the Kinetic Parameters of the Sodium Insertion in Sodium Molybdates by Impedance Spectroscopy

Abstract

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