TY - JOUR
T1 - Electron transfer photochemistry of bridged allylcyclopropane systems
T2 - Novel substitution products via deprotonation
AU - Zhou, Dahui
AU - Chou, Jolene
AU - Roth, Heinz D.
PY - 1999/12
Y1 - 1999/12
N2 - The electron transfer photochemistry of three rigid, bridged allylcyclopropane systems. 3-carene (1), tricyclo[4.3.1.01,6]dec-3-ene (2) and trricyclo[4.4.1.01,6]undeca-3,8-diene (3), is shown to take an unprecedented course: the major products are novel 'substitution' products, in which a hydrogen at an allylic carbon (C2) of the substrate has been replaced by the p-cyanophenyl group.
AB - The electron transfer photochemistry of three rigid, bridged allylcyclopropane systems. 3-carene (1), tricyclo[4.3.1.01,6]dec-3-ene (2) and trricyclo[4.4.1.01,6]undeca-3,8-diene (3), is shown to take an unprecedented course: the major products are novel 'substitution' products, in which a hydrogen at an allylic carbon (C2) of the substrate has been replaced by the p-cyanophenyl group.
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U2 - 10.1002/(SICI)1099-1395(199912)12:12<867::AID-POC206>3.0.CO;2-G
DO - 10.1002/(SICI)1099-1395(199912)12:12<867::AID-POC206>3.0.CO;2-G
M3 - Article
AN - SCOPUS:0042791182
SN - 0894-3230
VL - 12
SP - 867
EP - 874
JO - Journal of Physical Organic Chemistry
JF - Journal of Physical Organic Chemistry
IS - 12
ER -