Electrophilic and nucleophilic displacement reactions at the bridgehead borons of tris(pyridyl)borate scorpionate complexes

Joydeb Goura; James McQuade; Daisuke Shimoyama; Roger A. Lalancette; John B. Sheridan; Frieder Jäkle

doi:10.1039/d1cc06181j

Electrophilic and nucleophilic displacement reactions at the bridgehead borons of tris(pyridyl)borate scorpionate complexes

Joydeb Goura, James McQuade, Daisuke Shimoyama, Roger A. Lalancette, John B. Sheridan, Frieder Jäkle

Rutgers Newark, Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Although a wide variety of boron-based "scorpionate"ligands have been implemented, a modular route that offers facile access to different substitution patterns at boron has yet to be developed. Here, we demonstrate new reactivity patterns at the bridgehead positions of a ruthenium tris(pyrid-2-yl)borate complex that allow for facile tuning of steric and electronic properties.

Original language	English (US)
Pages (from-to)	977-980
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	7
DOIs	https://doi.org/10.1039/d1cc06181j
State	Published - Jan 21 2022

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d1cc06181j

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AU - Goura, Joydeb

AU - McQuade, James

AU - Shimoyama, Daisuke

AU - Lalancette, Roger A.

AU - Sheridan, John B.

AU - Jäkle, Frieder

N1 - Publisher Copyright: © The Royal Society of Chemistry.

PY - 2022/1/21

Y1 - 2022/1/21

N2 - Although a wide variety of boron-based "scorpionate"ligands have been implemented, a modular route that offers facile access to different substitution patterns at boron has yet to be developed. Here, we demonstrate new reactivity patterns at the bridgehead positions of a ruthenium tris(pyrid-2-yl)borate complex that allow for facile tuning of steric and electronic properties.

AB - Although a wide variety of boron-based "scorpionate"ligands have been implemented, a modular route that offers facile access to different substitution patterns at boron has yet to be developed. Here, we demonstrate new reactivity patterns at the bridgehead positions of a ruthenium tris(pyrid-2-yl)borate complex that allow for facile tuning of steric and electronic properties.

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Electrophilic and nucleophilic displacement reactions at the bridgehead borons of tris(pyridyl)borate scorpionate complexes

Abstract

All Science Journal Classification (ASJC) codes

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