Eliminations from 2H-Heptafluorobut-2-ene

Richard D. Chambers, Alex J. Roche

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

Various approaches are described for dehydrofluorination of heptafluorobut-2-ene (2) to give hexafluorobut-2-yne (1). Molecular sieve is particularly successful. Reaction of (2) with 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) surprisingly gave the novel heterocycle (8) via initial nucleophilic attack. Reactions of (2) with other bases are also described.

Original languageEnglish (US)
Pages (from-to)121-124
Number of pages4
JournalJournal of Fluorine Chemistry
Volume79
Issue number2
DOIs
StatePublished - Aug 1 1996
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Environmental Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Keywords

  • Heptafluorobut-2-ene

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