First innermolecular Diels-Alder reaction of o-benzyne inside a molecular container compound

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Abstract

1,2-Didehydrobenzene 1, incarcerated in the inner phase of a hemicarcerand 2, undergoes an innermolecular Diels-Alder reaction with its surrounding host, which is a new type of reaction at the borderline between intra- and intermolecular reactions.

Original languageEnglish (US)
Pages (from-to)59-60
Number of pages2
JournalChemical Communications
Issue number1
DOIs
StatePublished - Jan 7 1998
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • General Chemistry
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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