Fluorinated thiolates of divalent and trivalent lanthanides. Ln-F bonds and the synthesis of LnF3

J. H. Melman; T. J. Emge; J. G. Brennan

doi:10.1021/ic0006908

Fluorinated thiolates of divalent and trivalent lanthanides. Ln-F bonds and the synthesis of LnF₃

J. H. Melman, T. J. Emge, J. G. Brennan

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Fluorinated thiolates from particularly stable chalcogenolate complexes with the lanthanides. Both Sm-(SC₆F₅)₃ and Eu(SC₆F₅)₂ were prepared by transmetalation. The Sm compopund is a dimer in the solid state, with a pair of bridging thiolate ligands connecting the two Sm(III) ions, while the Eu(II) compound is polymeric. In both compounds there are clearly define Ln - F interactions. Thermolysis of the Sm compound gives SmF₃ and (C₆F₄S)_n (n = 2, 3, 4).

Original language	English (US)
Pages (from-to)	1078-1081
Number of pages	4
Journal	Inorganic Chemistry
Volume	40
Issue number	5
DOIs	https://doi.org/10.1021/ic0006908
State	Published - Feb 26 2001

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "Fluorinated thiolates from particularly stable chalcogenolate complexes with the lanthanides. Both Sm-(SC6F5)3 and Eu(SC6F5)2 were prepared by transmetalation. The Sm compopund is a dimer in the solid state, with a pair of bridging thiolate ligands connecting the two Sm(III) ions, while the Eu(II) compound is polymeric. In both compounds there are clearly define Ln - F interactions. Thermolysis of the Sm compound gives SmF3 and (C6F4S)n (n = 2, 3, 4).",

author = "Melman, {J. H.} and Emge, {T. J.} and Brennan, {J. G.}",

year = "2001",

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AU - Melman, J. H.

AU - Emge, T. J.

AU - Brennan, J. G.

PY - 2001/2/26

Y1 - 2001/2/26

N2 - Fluorinated thiolates from particularly stable chalcogenolate complexes with the lanthanides. Both Sm-(SC6F5)3 and Eu(SC6F5)2 were prepared by transmetalation. The Sm compopund is a dimer in the solid state, with a pair of bridging thiolate ligands connecting the two Sm(III) ions, while the Eu(II) compound is polymeric. In both compounds there are clearly define Ln - F interactions. Thermolysis of the Sm compound gives SmF3 and (C6F4S)n (n = 2, 3, 4).

AB - Fluorinated thiolates from particularly stable chalcogenolate complexes with the lanthanides. Both Sm-(SC6F5)3 and Eu(SC6F5)2 were prepared by transmetalation. The Sm compopund is a dimer in the solid state, with a pair of bridging thiolate ligands connecting the two Sm(III) ions, while the Eu(II) compound is polymeric. In both compounds there are clearly define Ln - F interactions. Thermolysis of the Sm compound gives SmF3 and (C6F4S)n (n = 2, 3, 4).

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Fluorinated thiolates of divalent and trivalent lanthanides. Ln-F bonds and the synthesis of LnF₃

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