Abstract
Fluorinated thiolates from particularly stable chalcogenolate complexes with the lanthanides. Both Sm-(SC6F5)3 and Eu(SC6F5)2 were prepared by transmetalation. The Sm compopund is a dimer in the solid state, with a pair of bridging thiolate ligands connecting the two Sm(III) ions, while the Eu(II) compound is polymeric. In both compounds there are clearly define Ln - F interactions. Thermolysis of the Sm compound gives SmF3 and (C6F4S)n (n = 2, 3, 4).
Original language | English (US) |
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Pages (from-to) | 1078-1081 |
Number of pages | 4 |
Journal | Inorganic Chemistry |
Volume | 40 |
Issue number | 5 |
DOIs | |
State | Published - Feb 26 2001 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry