Fluorophenoxycarbene inside a hemicarcerand: A bottled singlet carbene

Xuejun Liu, Gaosheng Chu, Robert A. Moss, Ronald R. Sauers, Ralf Warmuth

Research output: Contribution to journalArticle

43 Scopus citations

Abstract

Long live the carbene: Longevity is granted to fluorophenoxycarbene when it is generated photochemically from fluorophenoxydiazirine (see picture) inside a hemicarcerand. This fleeting, and otherwise nonisolable, singlet carbene is the first electron-deficient species that has been stabilized by trapping. NOE experiments suggest that the carbene adopts the intrinsically less stable cis conformation in the confined inner phase. (Chemical Equation Presented).

Original languageEnglish (US)
Pages (from-to)1994-1997
Number of pages4
JournalAngewandte Chemie - International Edition
Volume44
Issue number13
DOIs
StatePublished - Mar 18 2005

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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