Formation of non-centrosymmetric dimers in (1S*,4aR*,8aR*)-decahydronaphthalene-1-carboxylic acid

Mark Davison; Roger A. Lalancette; Hugh W. Thompson

doi:10.1107/S1600536805006410

Formation of non-centrosymmetric dimers in (1S,4aR,8aR*)-decahydronaphthalene-1-carboxylic acid

Mark Davison, Roger A. Lalancette, Hugh W. Thompson

SASN Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The all-cis racemate of the title compound, C₁₁H ₁₈O₂, crystallizes in the chair-chair conformation that places the carboxyl group in an equatorial postion. The space group is centrosymmetric but the compound aggregates as dimers whose components are related by a C₂ axis [O⋯O = 2.665 (3) Å and O-H⋯O = 177°]. In the crystal structure, one C-H⋯O=C close contact is found.

Original language	English (US)
Pages (from-to)	o877-o879
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	4
DOIs	https://doi.org/10.1107/S1600536805006410
State	Published - Apr 2005

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Formation of non-centrosymmetric dimers in (1S*,4aR*,8aR*)-decahydronaphthalene-1-carboxylic acid",

abstract = "The all-cis racemate of the title compound, C11H 18O2, crystallizes in the chair-chair conformation that places the carboxyl group in an equatorial postion. The space group is centrosymmetric but the compound aggregates as dimers whose components are related by a C2 axis [O⋯O = 2.665 (3) {\AA} and O-H⋯O = 177°]. In the crystal structure, one C-H⋯O=C close contact is found.",

author = "Mark Davison and Lalancette, {Roger A.} and Thompson, {Hugh W.}",

year = "2005",

month = apr,

doi = "10.1107/S1600536805006410",

language = "English (US)",

volume = "61",

pages = "o877--o879",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Formation of non-centrosymmetric dimers in (1S*,4aR*,8aR*)-decahydronaphthalene-1-carboxylic acid

AU - Davison, Mark

AU - Lalancette, Roger A.

AU - Thompson, Hugh W.

PY - 2005/4

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N2 - The all-cis racemate of the title compound, C11H 18O2, crystallizes in the chair-chair conformation that places the carboxyl group in an equatorial postion. The space group is centrosymmetric but the compound aggregates as dimers whose components are related by a C2 axis [O⋯O = 2.665 (3) Å and O-H⋯O = 177°]. In the crystal structure, one C-H⋯O=C close contact is found.

AB - The all-cis racemate of the title compound, C11H 18O2, crystallizes in the chair-chair conformation that places the carboxyl group in an equatorial postion. The space group is centrosymmetric but the compound aggregates as dimers whose components are related by a C2 axis [O⋯O = 2.665 (3) Å and O-H⋯O = 177°]. In the crystal structure, one C-H⋯O=C close contact is found.

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