(-)-Gibberic acid: Hydrogen-bonding pattern of the monohydrate of a non-racemic tetracyclic δ-keto acid derivative of gibberellin A3

Hugh W. Thompson, Roger Lalancette

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The crystal structure and hydrogen-bonding pattern of the monohydrate of gibberic acid was reported. The synthesis of the compound proceeded through a degradation mechanism involving aromatization, hydrolysis, decarboxylation and dehrydration. The geometry of hydrogen bonding was established with respect to the deviation of carbonyl groups from axial and planar symmetry.

Original languageEnglish (US)
Pages (from-to)841-843
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume57
Issue number7
DOIs
StatePublished - Jul 1 2001

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gibberellins
Keto Acids
Hydrogen Bonding
Hydrogen bonds
Derivatives
Aromatization
decarboxylation
acids
Decarboxylation
hydrogen
hydrolysis
Hydrolysis
Crystal structure
degradation
deviation
Degradation
crystal structure
Geometry
symmetry
synthesis

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

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abstract = "The crystal structure and hydrogen-bonding pattern of the monohydrate of gibberic acid was reported. The synthesis of the compound proceeded through a degradation mechanism involving aromatization, hydrolysis, decarboxylation and dehrydration. The geometry of hydrogen bonding was established with respect to the deviation of carbonyl groups from axial and planar symmetry.",
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