Highly luminescent, electron-deficient bora-cyclophanes

Pangkuan Chen, Frieder Jäkle

Research output: Contribution to journalArticlepeer-review

93 Scopus citations

Abstract

A highly luminescent conjugated organoboron macrocycle containing six Lewis acidic boron centers was synthesized. Comparison of the optical and electronic properties with those of a hexameric linear oligomer revealed important differences due to delocalization within the highly symmetric cyclic conjugated structure. Exposure of this unique electron-deficient bora-cyclophane to fluoride or cyanide results in amplified fluorescence quenching and can be exploited to switch between an electron-deficient macrocycle and a highly charged, electron-rich borate cycle.

Original languageEnglish (US)
Pages (from-to)20142-20145
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number50
DOIs
StatePublished - Dec 21 2011

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Fingerprint Dive into the research topics of 'Highly luminescent, electron-deficient bora-cyclophanes'. Together they form a unique fingerprint.

Cite this