Innermolecular reactions of fluorophenylcarbene inside a hemicarcerand

Zhifeng Lu, Robert A. Moss, Ronald R. Sauers, Ralf Warmuth

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

Photolysis of fluorophenyldiazirine, incarcerated in hemicarcerand 2, affords fluorophenylcarbene, which attacks an aryl unit of the host, leading (after rearrangement) to a fluoromethoxy/phenyltropone derivative of the hemicarcerand. The incarcerated carbene is probably unstable at temperatures above 100 K.

Original languageEnglish (US)
Pages (from-to)3866-3869
Number of pages4
JournalOrganic letters
Volume11
Issue number17
DOIs
StatePublished - Sep 3 2009

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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