Innermolecular reactions of fluorophenylcarbene inside a hemicarcerand

Zhifeng Lu; Robert A. Moss; Ronald R. Sauers; Ralf Warmuth

doi:10.1021/ol901474u

Innermolecular reactions of fluorophenylcarbene inside a hemicarcerand

Zhifeng Lu, Robert A. Moss, Ronald R. Sauers, Ralf Warmuth

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Photolysis of fluorophenyldiazirine, incarcerated in hemicarcerand 2, affords fluorophenylcarbene, which attacks an aryl unit of the host, leading (after rearrangement) to a fluoromethoxy/phenyltropone derivative of the hemicarcerand. The incarcerated carbene is probably unstable at temperatures above 100 K.

Original language	English (US)
Pages (from-to)	3866-3869
Number of pages	4
Journal	Organic letters
Volume	11
Issue number	17
DOIs	https://doi.org/10.1021/ol901474u
State	Published - Sep 3 2009

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol901474u

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title = "Innermolecular reactions of fluorophenylcarbene inside a hemicarcerand",

abstract = "Photolysis of fluorophenyldiazirine, incarcerated in hemicarcerand 2, affords fluorophenylcarbene, which attacks an aryl unit of the host, leading (after rearrangement) to a fluoromethoxy/phenyltropone derivative of the hemicarcerand. The incarcerated carbene is probably unstable at temperatures above 100 K.",

author = "Zhifeng Lu and Moss, {Robert A.} and Sauers, {Ronald R.} and Ralf Warmuth",

year = "2009",

month = sep,

day = "3",

doi = "10.1021/ol901474u",

language = "English (US)",

volume = "11",

pages = "3866--3869",

journal = "Organic letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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T1 - Innermolecular reactions of fluorophenylcarbene inside a hemicarcerand

AU - Lu, Zhifeng

AU - Moss, Robert A.

AU - Sauers, Ronald R.

AU - Warmuth, Ralf

PY - 2009/9/3

Y1 - 2009/9/3

N2 - Photolysis of fluorophenyldiazirine, incarcerated in hemicarcerand 2, affords fluorophenylcarbene, which attacks an aryl unit of the host, leading (after rearrangement) to a fluoromethoxy/phenyltropone derivative of the hemicarcerand. The incarcerated carbene is probably unstable at temperatures above 100 K.

AB - Photolysis of fluorophenyldiazirine, incarcerated in hemicarcerand 2, affords fluorophenylcarbene, which attacks an aryl unit of the host, leading (after rearrangement) to a fluoromethoxy/phenyltropone derivative of the hemicarcerand. The incarcerated carbene is probably unstable at temperatures above 100 K.

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M3 - Article

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EP - 3869

JO - Organic letters

JF - Organic letters

IS - 17

ER -

Innermolecular reactions of fluorophenylcarbene inside a hemicarcerand

Abstract

All Science Journal Classification (ASJC) codes

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