Integral equation theories for monodisperse and polydisperse sticky hard sphere chain fluid: Thermodynamic and structural properties in the polymer Percus-Yevick and ideal chain approximations

Ning Wu; S. S. Feng; Y. C. Chiew

doi:10.1063/1.1575199

Integral equation theories for monodisperse and polydisperse sticky hard sphere chain fluid: Thermodynamic and structural properties in the polymer Percus-Yevick and ideal chain approximations

Ning Wu, S. S. Feng, Y. C. Chiew

School of Engineering, Chemical & Biochemical Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The multi-density Ornstein-Zernike (MOZ) integral equation theory was used to model a homonuclear sticky hard sphere (SHS) chain fluid in the context of the polymer Percus-Yevick (PPY) and ideal chain approximations. It was found that for a nonathermal system, the difference of structural properties between a monodisperse and a polydisperse system is not of significance only at intermediate and high densities. The Helmholtz energy, pressure, and phase coexistence of the monodisperse SHS chains were computed via the energy route.

Original language	English (US)
Pages (from-to)	10794-10807
Number of pages	14
Journal	Journal of Chemical Physics
Volume	118
Issue number	23
DOIs	https://doi.org/10.1063/1.1575199
State	Published - Jun 15 2003

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Access to Document

10.1063/1.1575199

Cite this

@article{4d6654bfa454491a8fcc3cb74653a7b8,

title = "Integral equation theories for monodisperse and polydisperse sticky hard sphere chain fluid: Thermodynamic and structural properties in the polymer Percus-Yevick and ideal chain approximations",

abstract = "The multi-density Ornstein-Zernike (MOZ) integral equation theory was used to model a homonuclear sticky hard sphere (SHS) chain fluid in the context of the polymer Percus-Yevick (PPY) and ideal chain approximations. It was found that for a nonathermal system, the difference of structural properties between a monodisperse and a polydisperse system is not of significance only at intermediate and high densities. The Helmholtz energy, pressure, and phase coexistence of the monodisperse SHS chains were computed via the energy route.",

author = "Ning Wu and Feng, {S. S.} and Chiew, {Y. C.}",

year = "2003",

month = jun,

day = "15",

doi = "10.1063/1.1575199",

language = "English (US)",

volume = "118",

pages = "10794--10807",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics Publising LLC",

number = "23",

}

Integral equation theories for monodisperse and polydisperse sticky hard sphere chain fluid: Thermodynamic and structural properties in the polymer Percus-Yevick and ideal chain approximations. / Wu, Ning; Feng, S. S.; Chiew, Y. C.
In: Journal of Chemical Physics, Vol. 118, No. 23, 15.06.2003, p. 10794-10807.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Integral equation theories for monodisperse and polydisperse sticky hard sphere chain fluid

T2 - Thermodynamic and structural properties in the polymer Percus-Yevick and ideal chain approximations

AU - Wu, Ning

AU - Feng, S. S.

AU - Chiew, Y. C.

PY - 2003/6/15

Y1 - 2003/6/15

N2 - The multi-density Ornstein-Zernike (MOZ) integral equation theory was used to model a homonuclear sticky hard sphere (SHS) chain fluid in the context of the polymer Percus-Yevick (PPY) and ideal chain approximations. It was found that for a nonathermal system, the difference of structural properties between a monodisperse and a polydisperse system is not of significance only at intermediate and high densities. The Helmholtz energy, pressure, and phase coexistence of the monodisperse SHS chains were computed via the energy route.

AB - The multi-density Ornstein-Zernike (MOZ) integral equation theory was used to model a homonuclear sticky hard sphere (SHS) chain fluid in the context of the polymer Percus-Yevick (PPY) and ideal chain approximations. It was found that for a nonathermal system, the difference of structural properties between a monodisperse and a polydisperse system is not of significance only at intermediate and high densities. The Helmholtz energy, pressure, and phase coexistence of the monodisperse SHS chains were computed via the energy route.

UR - http://www.scopus.com/inward/record.url?scp=0038203371&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0038203371&partnerID=8YFLogxK

U2 - 10.1063/1.1575199

DO - 10.1063/1.1575199

M3 - Article

AN - SCOPUS:0038203371

SN - 0021-9606

VL - 118

SP - 10794

EP - 10807

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 23

ER -

Integral equation theories for monodisperse and polydisperse sticky hard sphere chain fluid: Thermodynamic and structural properties in the polymer Percus-Yevick and ideal chain approximations

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this