The multi-density Ornstein-Zernike (MOZ) integral equation theory was used to model a homonuclear sticky hard sphere (SHS) chain fluid in the context of the polymer Percus-Yevick (PPY) and ideal chain approximations. It was found that for a nonathermal system, the difference of structural properties between a monodisperse and a polydisperse system is not of significance only at intermediate and high densities. The Helmholtz energy, pressure, and phase coexistence of the monodisperse SHS chains were computed via the energy route.
All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry