Intriguing transport dynamics of ethylammonium nitrate-acetonitrile binary mixtures arising from nano-inhomogeneity

Alessandro Mariani; Matteo Bonomo; Boning Wu; Barbara Centrella; Danilo Dini; Edward W. Castner; Lorenzo Gontrani

doi:10.1039/c7cp04592a

Intriguing transport dynamics of ethylammonium nitrate-acetonitrile binary mixtures arising from nano-inhomogeneity

Alessandro Mariani, Matteo Bonomo, Boning Wu, Barbara Centrella, Danilo Dini, Edward W. Castner, Lorenzo Gontrani

School of Arts and Sciences, Chemistry & Chemical Biology

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Binary mixtures of ethylammonium nitrate and acetonitrile show interesting properties that originate from the structural and dynamical nano-heterogeneity present in ionic liquids. These effects are most pronounced when the ionic liquid is the minority compound. In this study the transport properties of such mixtures are studied, including viscosity, self-diffusion and conductivity. The results strongly support the presence of structural inhomogeneity and show an interesting composition-dependent behaviour in the mixtures.

Original language	English (US)
Pages (from-to)	27212-27220
Number of pages	9
Journal	Physical Chemistry Chemical Physics
Volume	19
Issue number	40
DOIs	https://doi.org/10.1039/c7cp04592a
State	Published - 2017

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1039/c7cp04592a

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title = "Intriguing transport dynamics of ethylammonium nitrate-acetonitrile binary mixtures arising from nano-inhomogeneity",

abstract = "Binary mixtures of ethylammonium nitrate and acetonitrile show interesting properties that originate from the structural and dynamical nano-heterogeneity present in ionic liquids. These effects are most pronounced when the ionic liquid is the minority compound. In this study the transport properties of such mixtures are studied, including viscosity, self-diffusion and conductivity. The results strongly support the presence of structural inhomogeneity and show an interesting composition-dependent behaviour in the mixtures.",

author = "Alessandro Mariani and Matteo Bonomo and Boning Wu and Barbara Centrella and Danilo Dini and Castner, {Edward W.} and Lorenzo Gontrani",

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T1 - Intriguing transport dynamics of ethylammonium nitrate-acetonitrile binary mixtures arising from nano-inhomogeneity

AU - Mariani, Alessandro

AU - Bonomo, Matteo

AU - Wu, Boning

AU - Centrella, Barbara

AU - Dini, Danilo

AU - Castner, Edward W.

AU - Gontrani, Lorenzo

PY - 2017

Y1 - 2017

N2 - Binary mixtures of ethylammonium nitrate and acetonitrile show interesting properties that originate from the structural and dynamical nano-heterogeneity present in ionic liquids. These effects are most pronounced when the ionic liquid is the minority compound. In this study the transport properties of such mixtures are studied, including viscosity, self-diffusion and conductivity. The results strongly support the presence of structural inhomogeneity and show an interesting composition-dependent behaviour in the mixtures.

AB - Binary mixtures of ethylammonium nitrate and acetonitrile show interesting properties that originate from the structural and dynamical nano-heterogeneity present in ionic liquids. These effects are most pronounced when the ionic liquid is the minority compound. In this study the transport properties of such mixtures are studied, including viscosity, self-diffusion and conductivity. The results strongly support the presence of structural inhomogeneity and show an interesting composition-dependent behaviour in the mixtures.

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JF - Physical Chemistry Chemical Physics

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ER -

Intriguing transport dynamics of ethylammonium nitrate-acetonitrile binary mixtures arising from nano-inhomogeneity

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