Ionization, excitation of high-lying atomic states, and molecular fluorescence in Cs vapor excited at =455.7 and 459.4 nm

J. Huennekens, Z. Wu, T. G. Walker

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Abstract

We have studied in detail the ionization and population of high-lying atomic states which occur in cesium vapor excited at the second resonance transition, 6S-7P. We have developed a simple model which qualitatively explains the laser-power dependences of level populations and electron densities which we observed. Measurements of spatial dependences of fluorescence point out the critical role of radiation trapping in these phenomena. Similar observations on rubidium demonstrate the same type of behavior when the first (5S-5P) or second (5S-6P) resonance is excited. At higher densities and temperatures we found that the fluorescence was dominated by diffuse molecular bands. Some of these bands probably consist of transitions to the repulsive u+3 state. Additionally four bands observed at 817.5, 826.6, 835.3, and 839.6 nm are tentatively identified as the cesium analog of the g33u+ satellite bands which have previously been observed in the blue wing of the first resonance doublet of the lighter alkali metals.

Original languageEnglish (US)
Pages (from-to)196-209
Number of pages14
JournalPhysical Review A
Volume31
Issue number1
DOIs
StatePublished - 1985
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Atomic and Molecular Physics, and Optics

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