Kinetics of transformation for anisotropic particles including shielding effects

Dunbar P. Birnie, Michael C. Weinberg

Research output: Contribution to journalArticlepeer-review

56 Scopus citations

Abstract

A derivation is presented for X(t), the transformed fraction as a function of time, in a phase transformation process which produces randomly oriented anisotropic particles. The key novel element in the development and results is the inclusion of blocking (shielding) effects. The derivation is performed for a 2D system in which symmetrical particles of arbitrary shape are formed. In addition, approximate calculations are performed for X(t) for the case of elliptical particles in order to estimate the influence of growth rate anisotropy upon the magnitude of the blocking effects.

Original languageEnglish (US)
Pages (from-to)3742-3746
Number of pages5
JournalThe Journal of Chemical Physics
Volume103
Issue number9
DOIs
StatePublished - Jan 1 1995
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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