Lewis acidity enhancement of organoboranes via oxidation of appended ferrocene moieties

Krishnan Venkatasubbaiah; Israel Nowik; Rolfe H. Herber; Frieder Jäkle

doi:10.1039/b701807j

Lewis acidity enhancement of organoboranes via oxidation of appended ferrocene moieties

Krishnan Venkatasubbaiah, Israel Nowik, Rolfe H. Herber, Frieder Jäkle

Rutgers Newark, Chemistry

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

The Lewis acidity of boron in diboradiferrocene 1 is strongly enhanced through oxidation of the iron atoms as evident from examination of X-ray structural parameters of the mixed-valent cation 1⁺PF₆ and further confirmed from the strong complexation of MeCN to the dication in 2²⁺(I₃)₂.

Original language	English (US)
Pages (from-to)	2154-2156
Number of pages	3
Journal	Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/b701807j
State	Published - 2007

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b701807j

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title = "Lewis acidity enhancement of organoboranes via oxidation of appended ferrocene moieties",

abstract = "The Lewis acidity of boron in diboradiferrocene 1 is strongly enhanced through oxidation of the iron atoms as evident from examination of X-ray structural parameters of the mixed-valent cation 1+PF6 and further confirmed from the strong complexation of MeCN to the dication in 22+(I3)2.",

author = "Krishnan Venkatasubbaiah and Israel Nowik and Herber, {Rolfe H.} and Frieder J{\"a}kle",

year = "2007",

doi = "10.1039/b701807j",

language = "English (US)",

pages = "2154--2156",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Lewis acidity enhancement of organoboranes via oxidation of appended ferrocene moieties

AU - Venkatasubbaiah, Krishnan

AU - Nowik, Israel

AU - Herber, Rolfe H.

AU - Jäkle, Frieder

PY - 2007

Y1 - 2007

N2 - The Lewis acidity of boron in diboradiferrocene 1 is strongly enhanced through oxidation of the iron atoms as evident from examination of X-ray structural parameters of the mixed-valent cation 1+PF6 and further confirmed from the strong complexation of MeCN to the dication in 22+(I3)2.

AB - The Lewis acidity of boron in diboradiferrocene 1 is strongly enhanced through oxidation of the iron atoms as evident from examination of X-ray structural parameters of the mixed-valent cation 1+PF6 and further confirmed from the strong complexation of MeCN to the dication in 22+(I3)2.

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DO - 10.1039/b701807j

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C2 - 17520120

AN - SCOPUS:34548203786

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EP - 2156

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Lewis acidity enhancement of organoboranes via oxidation of appended ferrocene moieties

Abstract

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