Magnetic Field Dependence of 19F Nuclear Spin Polarization. The System Tetrafluorobenzoquinone-Tetrafluorohydroquinone

Richard S. Hutton, Heinz D. Roth, Marcia L. Manion Schilling, Anthony M. Trozzolo, Thomas M. Leslie

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The magnetic field dependence of the 19F polarization observed in the reaction of tetrafluorobenzoquinone with tetrafluorohydroquinone in benzene has been studied. The results can be interpreted in terms of three different polarization mechanisms. The effects observed at fields below 100 G can be ascribed to a radical-pair mechanism involving S-T± mixing. At fields of 1–20 kG two different contributions have been identified which can be observed separately under appropriate experimental conditions. One contribution showing a maximum near 4 kG is assigned to a biradical adduct between the triplet quinone and the solvent, benzene. The other contribution shows a monotonical increase with magnetic field strength. This effect is assigned to the triplet-Overhauser mechanism in the reaction of the triplet quinone with the hydroquinone.

Original languageEnglish (US)
Pages (from-to)5878-5883
Number of pages6
JournalJournal of the American Chemical Society
Volume104
Issue number22
DOIs
StatePublished - Jan 1 1982

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Spin polarization
Magnetic Fields
Benzene
Polarization
Magnetic fields
benzoquinone
hydroquinone

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Hutton, Richard S. ; Roth, Heinz D. ; Manion Schilling, Marcia L. ; Trozzolo, Anthony M. ; Leslie, Thomas M. / Magnetic Field Dependence of 19F Nuclear Spin Polarization. The System Tetrafluorobenzoquinone-Tetrafluorohydroquinone. In: Journal of the American Chemical Society. 1982 ; Vol. 104, No. 22. pp. 5878-5883.
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Magnetic Field Dependence of 19F Nuclear Spin Polarization. The System Tetrafluorobenzoquinone-Tetrafluorohydroquinone. / Hutton, Richard S.; Roth, Heinz D.; Manion Schilling, Marcia L.; Trozzolo, Anthony M.; Leslie, Thomas M.

In: Journal of the American Chemical Society, Vol. 104, No. 22, 01.01.1982, p. 5878-5883.

Research output: Contribution to journalArticle

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AU - Hutton, Richard S.

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AB - The magnetic field dependence of the 19F polarization observed in the reaction of tetrafluorobenzoquinone with tetrafluorohydroquinone in benzene has been studied. The results can be interpreted in terms of three different polarization mechanisms. The effects observed at fields below 100 G can be ascribed to a radical-pair mechanism involving S-T± mixing. At fields of 1–20 kG two different contributions have been identified which can be observed separately under appropriate experimental conditions. One contribution showing a maximum near 4 kG is assigned to a biradical adduct between the triplet quinone and the solvent, benzene. The other contribution shows a monotonical increase with magnetic field strength. This effect is assigned to the triplet-Overhauser mechanism in the reaction of the triplet quinone with the hydroquinone.

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