Abstract
We investigate the properties of binary mixtures of hard-sphere fluids with nonadditive diameters: calling Rij- the distance of closest approach between particles of species i and j we assume R12=1/2(R 11+R22)+α with α≠0. We find the exact correlation functions as well as the solution of the Percus-Yevick integral equation for this system with 0≤α<1/2(R22-R 11), in one dimension. For the three-dimensional case the Percus-Yevick equation is solved partially.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 3335-3346 |
| Number of pages | 12 |
| Journal | The Journal of Chemical Physics |
| Volume | 54 |
| Issue number | 8 |
| DOIs | |
| State | Published - Jan 1 1971 |
| Externally published | Yes |
All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Lebowitz, J., & Zomick, D. (1971). Mixtures of hard spheres with nonadditive diameters: Some exact results and solution of PY equation. The Journal of Chemical Physics, 54(8), 3335-3346. https://doi.org/10.1063/1.1675348