Molecular host-guest complexes: Shielding of guests on semiconductor surfaces

Marina Freitag, Elena Galoppini

Research output: Contribution to journalReview article

35 Citations (Scopus)

Abstract

A recent and promising development in the field of renewable energy is the use of molecular containers (cyclodextrins, cucurbiturils, Cram-type hosts, and calixarenes) to bind encapsulated chromophores or redox-active compounds to the surface of TiO2 nanoparticles and other nanostructured wide bandgap metal oxide semiconductors. The host provides an alternative method of adsorption of molecules on semiconductors and shields the guest from the heterogenous interface. The novel hybrid systems exhibited photophysical and electrochemical properties that differ from the properties of layers obtained by directly attaching the chromophore to the semiconductor through binding groups, including slower and homogeneous interfacial electron recombination dynamics. In addition to DSSCs, the guest@host/semiconductor systems find applications as sensors, electrochromic windows, and LEDs.

Original languageEnglish (US)
Pages (from-to)2482-2494
Number of pages13
JournalEnergy and Environmental Science
Volume4
Issue number7
DOIs
StatePublished - Jul 1 2011

Fingerprint

Shielding
Chromophores
Semiconductor materials
Calixarenes
Cyclodextrins
Hybrid systems
Electrochemical properties
Light emitting diodes
Containers
Energy gap
Metals
recombination
Nanoparticles
Adsorption
shield
Molecules
Electrons
Sensors
sensor
adsorption

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Pollution

Cite this

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Molecular host-guest complexes : Shielding of guests on semiconductor surfaces. / Freitag, Marina; Galoppini, Elena.

In: Energy and Environmental Science, Vol. 4, No. 7, 01.07.2011, p. 2482-2494.

Research output: Contribution to journalReview article

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