TY - JOUR
T1 - Nature and evolution of incommensurate charge order in manganites visualized with cryogenic scanning transmission electron microscopy
AU - Baggari, Ismail El
AU - Savitzky, Benjamin H.
AU - Admasu, Alemayehu S.
AU - Kim, Jaewook
AU - Cheong, Sang Wook
AU - Hovden, Robert
AU - Kourkoutis, Lena F.
N1 - Funding Information:
Research was primarily supported by the Department of Defense, Air Force Office of Scientific Research under Award FA 9550-16-1-0305. We also acknowledge support by the Packard Foundation. This work made use of the Cornell Center for Materials Research Shared Facilities, which are supported through the National Science Foundation (NSF) Materials Research Science and Engineering Centers (MRSEC) program (DMR-1719875). The FEI Titan Themis 300 was acquired through Grant NSF-MRI-1429155, with additional support from Cornell University, the Weill Institute, and the Kavli Institute at Cornell. B.H.S. was supported by NSF Graduate Research Fellowship Program (GRFP) Grant DGE-1144153. The work at Rutgers was supported by the Gordon and Betty Moore Foundation’s Emergent Phenomena in Quantum Systems (EPiQS) Initiative through Grant GBMF4413 to the Rutgers Center for Emergent Materials.
Funding Information:
ACKNOWLEDGMENTS. Research was primarily supported by the Department of Defense, Air Force Office of Scientific Research under Award FA 9550-16-1-0305. We also acknowledge support by the Packard Foundation. This work made use of the Cornell Center for Materials Research Shared Facilities, which are supported through the National Science Foundation (NSF) Materials Research Science and Engineering Centers (MRSEC) program (DMR-1719875). The FEI Titan Themis 300 was acquired through Grant NSF-MRI-1429155, with additional support from Cornell University, the Weill Institute, and the Kavli Institute at Cornell. B.H.S. was supported by NSF Graduate Research Fellowship Program (GRFP) Grant DGE-1144153. The work at Rutgers was supported by the Gordon and Betty Moore Foundation’s Emergent Phenomena in Quantum Systems (EPiQS) Initiative through Grant GBMF4413 to the Rutgers Center for Emergent Materials.
Publisher Copyright:
© 2018 National Academy of Sciences. All Rights Reserved.
PY - 2018/2/13
Y1 - 2018/2/13
N2 - Incommensurate charge order in hole-doped oxides is intertwined with exotic phenomena such as colossal magnetoresistance, high-temperature superconductivity, and electronic nematicity. Here, we map, at atomic resolution, the nature of incommensurate charge–lattice order in a manganite using scanning transmission electron microscopy at room temperature and cryogenic temperature (∼93 K). In diffraction, the ordering wave vector changes upon cooling, a behavior typically associated with incommensurate order. However, using real space measurements, we discover that the ordered state forms lattice-locked regions over a few wavelengths interspersed with phase defects and changing periodicity. The cations undergo picometer-scale (∼6 pm to 11 pm) transverse displacements, suggesting that charge–lattice coupling is strong. We further unearth phase inhomogeneity in the periodic lattice displacements at room temperature, and emergent phase coherence at 93 K. Such local phase variations govern the long-range correlations of the charge-ordered state and locally change the periodicity of the modulations, resulting in wave vector shifts in reciprocal space. These atomically resolved observations underscore the importance of lattice coupling and phase inhomogeneity, and provide a microscopic explanation for putative “incommensurate” order in hole-doped oxides.
AB - Incommensurate charge order in hole-doped oxides is intertwined with exotic phenomena such as colossal magnetoresistance, high-temperature superconductivity, and electronic nematicity. Here, we map, at atomic resolution, the nature of incommensurate charge–lattice order in a manganite using scanning transmission electron microscopy at room temperature and cryogenic temperature (∼93 K). In diffraction, the ordering wave vector changes upon cooling, a behavior typically associated with incommensurate order. However, using real space measurements, we discover that the ordered state forms lattice-locked regions over a few wavelengths interspersed with phase defects and changing periodicity. The cations undergo picometer-scale (∼6 pm to 11 pm) transverse displacements, suggesting that charge–lattice coupling is strong. We further unearth phase inhomogeneity in the periodic lattice displacements at room temperature, and emergent phase coherence at 93 K. Such local phase variations govern the long-range correlations of the charge-ordered state and locally change the periodicity of the modulations, resulting in wave vector shifts in reciprocal space. These atomically resolved observations underscore the importance of lattice coupling and phase inhomogeneity, and provide a microscopic explanation for putative “incommensurate” order in hole-doped oxides.
KW - Charge order
KW - Cryogenic STEM
KW - Electron microscopy
KW - Incommensurate
KW - Manganite
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UR - http://www.scopus.com/inward/citedby.url?scp=85041944287&partnerID=8YFLogxK
U2 - 10.1073/pnas.1714901115
DO - 10.1073/pnas.1714901115
M3 - Article
C2 - 29382750
AN - SCOPUS:85041944287
SN - 0027-8424
VL - 115
SP - 1445
EP - 1450
JO - Proceedings of the National Academy of Sciences of the United States of America
JF - Proceedings of the National Academy of Sciences of the United States of America
IS - 7
ER -